write an equation to represent the oxidation of an alcohol.
identify the reagents that may be used to oxidize a given alcohol.
identify the specific reagent that is used to oxidize primary alcohols to aldehydes rather than to carboxylic acids.
identify the product formed from the oxidation of a given alcohol with a specified oxidizing agent.
identify the alcohol needed to prepare a given aldehyde, ketone or carboxylic acid by simple oxidation.
write a mechanism for the oxidation of an alcohol using a chromium(VI) reagent.
The reading mentions that pyridinium chlorochromate (PCC) is a milder version of chromic acid that is suitable for converting a primary alcohol into an aldehyde without oxidizing it all the way to a carboxylic acid. This reagent is being replaced in laboratories by Dess‑Martin periodinane (DMP), which has several practical advantages over PCC, such as producing higher yields and requiring less rigorous reaction conditions. DMP is named after Daniel Dess and James Martin, who developed it in 1983.
This page looks at the oxidation of alcohols using acidified sodium or potassium dichromate(VI) solution. This reaction is used to make aldehydes, ketones and carboxylic acids, and as a way of distinguishing between primary, secondary and tertiary alcohols.
Oxidizing the different types of alcohols
The oxidizing agent used in these reactions is normally a solution of sodium or potassium dichromate(VI) acidified with dilute sulfuric acid. If oxidation occurs, the orange solution containing the dichromate(VI) ions is reduced to a green solution containing chromium(III) ions. The electron-half-equation for this reaction is
Cr2O2−7+14H++6e−→2Cr3++7H2O
The turkey limits bc you can make 9 sandwiches with 9 turkey and 12 sandwiches with 25 bread
Answer:
38.541 × 10¹⁹ formula units
Explanation:
Given data:
Mass of chromium sulfate = 0.25 g
Formula units in 0.25 g = ?
Solution:
The given problem will solve by using Avogadro number.
It is the number of atoms , ions and molecules in one gram atom of element, one gram molecules of compound and one gram ions of a substance.
The number 6.022 × 10²³ is called Avogadro number.
For example,
18 g of water = 1 mole = 6.022 × 10²³ formula units of water
Number of moles of chromium sulfate = Mass / molar mass
Number of moles of chromium sulfate = 0.25 g/ 392.16 g/ mol
Number of moles of chromium sulfate = 6.4 × 10⁻⁴ moles
Number of formula units:
1 mole = 6.022 × 10²³ formula units
6.4 × 10⁻⁴ moles × 6.022 × 10²³ formula units / 1 mol
38.541 × 10¹⁹ formula units
Answer:
0.677 moles
Explanation:
Take the atomic mass of K = 39.1, O =16.0, P = 31.0
no. of moles = mass / molar mass
no. of moles of K3PO4 used = 4.79 / (39.1x3 + 31 + 16x4)
= 0.02256 mol
From the equation, the mole ratio of KOH : K3PO4 = 3 :1,
meaning every 3 moles of KOH used, produces 1 mole of K3PO4.
So, using this ratio, let the no. of moles of KOH required to be y.
y = 0.02256 x3
y = 0.0677 mol
If you don't find exactly 0.677 moles as one of the options, go for the closest one. A very slight error may occur because of taking different significant figures of atomic masses when calculating.
