Answer:
The volume of the gas will be 78.31 L at 1.7 °C.
Explanation:
We can find the temperature of the gas by the ideal gas law equation:

Where:
n: is the number of moles
V: is the volume
T: is the temperature
R: is the gas constant = 0.082 L*atm/(K*mol)
From the initial we can find the number of moles:

Now, we can find the temperature with the final conditions:

The temperature in Celsius is:

Therefore, the volume of the gas will be 78.31 L at 1.7 °C.
I hope it helps you!
The correct answer would be “slightly negative”.
Answer:
a. 750Hz, b. 4.0ppm, c. 600Hz
Explanation:
The Downfield Shift (Hz) is given by the formula
Downfield Shift (Hz) = Chemical Shift (ppm) x Spectrometer Frequency (Hz)
Using the above formula we can solve all three parts easily
a. fspec = 300 MHz, Chem. Shift = 2.5ppm, 1MHz = 10⁶ Hz, 1ppm (parts per million) = 10⁻⁶
Downfield Shift (Hz) = 2.5ppm x 300MHz x (1Hz/10⁶MHz) x (10⁻⁶/1ppm)
Downfield Shift = 750 Hz
The signal is at 750Hz Downfield from TMS
b. Downfield Shift = 1200 Hz, Chemical Shift = ?
Chemical Shift = Downfield shift/Spectrometer Frequency
Chemical Shift = (1200Hz/300MHz) x (1ppm/10⁻⁶) = 4.0 ppm
The signal comes at 4.0 ppm
c. Separation of 2ppm, Downfield Shift = ?
Downfield Shift (Hz) = 2(ppm) x 300 (MHz) x (1Hz/10⁶MHz) x (10⁻⁶/1ppm) = 600 Hz
The two peaks are separated by 600Hz