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If a 95.27 mL sample of acetic acid (HC2H3O2) is titrated to the equivalence point with 79.06 mL of 0.113 M KOH, what is the pH

KATRIN_1 [288]

Answer:

8.73

Explanation:

The concentration of acetic acid can be determined as follows:

$M_1V_1 = M_2V_2\\(KOH) = (CH_3COOH)$

$M_{KOH}=0.113 M\\V_{KOH}=79.06 mL$

$V_{CH_3COOH}=95.27 \\\\M_{CH_3COOH)=?????$

$M_{CH3COOH} = \frac{M_{KOH}*V_{KOH}}{V_{CH_3COOH}}$

$M_{CH3COOH} = \frac{0.113*79.06}{95.27}$

$M_{CH3COOH} = 0.094 M$

Moles of $CH_3COOH$ = $95.27* 10^{-3}* 0.094$

=0.0090 moles

Moles of $KOH = 79.06*10^{-3}*0.113$

= 0.0090 moles

The equation for the reaction can be expressed as :

$CH_3COOH$ $+$ $KOH$ -----> $CH_3COO^{-}K^+$ $+$ $H_2O$

Concentration of $CH_3COO^{-$ ion = $\frac{0.0090}{Total volume (L)}$

= $\frac{0.0090}{(95.27+79.06)} *1000$

= 0.052 M

Hydrolysis of $CH_3COO^{-$ ion:

$CH_3COO^{-$ $+$ $H_2O$ -----> $CH_3COOH$ $+$ $OH^-$

$K = \frac{K_w}{K_a} = \frac{x*x}{0.052-x}$

⇒ $\frac{10^{-14}}{1.82*10^{-5}}= \frac{x*x}{0.052-x}$

= $0.5494*10^{-9}= \frac{x*x}{0.052-x}$

As K is so less, then x appears to be a very infinitesimal small number

0.052-x ≅ x

$0.5494*10^{-9}= \frac{x^2}{0.052}$

$x^2 = 0.5494*10^{-9}*0.052$

$x^2 = 0.286*10^{-10$

$x = \sqrt{0.286*10^{-10$

$x =0.535*10^{-5}M$

$[OH] = x =0.535*10^{-5}$

$pOH = -log[OH^-]$

$pOH = -log[0.535*10^{-5}]$

$pOH = 5.27$

pH = 14 - pOH

pH = 14 - 5.27

pH = 8.73

Hence, the pH of the titration mixture = 8.73

8 0

3 years ago

Place the following compounds in order of increasing strength of intermolecular forces. HF H2 CH3Cl

Scorpion4ik [409]

Answer:

H2 < CH3Cl < HF

Explanation:

The intermolecular forces are the forces that bond the molecules together in a substance. There are three types of these forces:

Dipole induced -dipole induced, or London dispersion -> Is the weakest and is presented in nonpolar molecules, in which a dipole is induced and so the molecules are joined together;
Dipole-dipole -> Is stronger than the London dispersion and occurs in a polar molecule. In this case, the dipole already exists (partial positive and negative charges), so the poles are attracted;
Hydrogen bond -> It's the strongest and is formed when the hydrogen is bonded with a higher electronegativity element (F, O, and N).

So, the molecule of H2 is linear and formed by the same element, so, is nonpolar, and has London dispersion forces. The molecule of CH3Cl has 3 nonpolar bonds (C-H), and one polar bond (C-Cl), so it's polar and has dipole-dipole forces. And the HF molecule has hydrogen bonds.

*A polar bond is a bond formed by elements with different electronegativities.

3 0

3 years ago

Car battery energy that makes device work

MAXImum [283]

Engine is it ok ksndjsjja

4 0

3 years ago

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When hydrochloric acid is poured on limestone, the mixture fizzes, releasing a colorless, odorless gas. The equation for this ch

ruslelena [56]

Answer:

pretty sure its B

Explanation:

7 0

2 years ago

Table salt contains 39.33 g of sodium per 100 g of salt. The U.S. Food and Drug Administration (FDA) recommends that adults cons

IrinaVladis [17]

<span>First set up the equation 39.33g/100g = x/1.28g and that'll give you how much sodium is in each 100g of the mix.

39.33g *1.28g= 100g * x
x = 0.503424g
x = Amount of sodium per 100g of the mix

Now 2.4g / 0.503424 = 4.7674
Multiply by 100 and you get 476.7353g</span>

4 0

3 years ago

Read 2 more answers