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Alex73 [517]
3 years ago
14

A sealed glass jar has a small amount of water on the bottom. The rest of the volume in the jar is taken up by helium gas at a p

artial pressure of 526 mmHg, and water vapor. If the total pressure inside the jar is 760. mmHg, what is the temperature of the water?
Chemistry
1 answer:
Natalija [7]3 years ago
8 0

<u>Answer:</u>

The temperature of the water is 70°C

<u>Explanation:</u>

Partial pressure of helium gas = 526 mmHg

Total pressure inside the jar= 760 mmHg

Suppose partial pressure of helium gas is P_H_e and partial pressure of water isP_H__2O

And total pressure is P_T

As we know

\mathrm{P}_{\mathrm{T}}=\mathrm{P}_{\mathrm{HE}}+\mathrm{P}_{\mathrm{H} 2 \mathrm{O}}

Hence

Putting the values  

760=526+\mathrm{P}_{\mathrm{H} 2 \mathrm{O}}

\mathrm{P}_{\mathrm{H} 2 \mathrm{O}}=760-526

\mathrm{P}_{\mathrm{H} 20}=234 \mathrm{mm} \mathrm{Hg}

In bar,

\mathrm{P}_{\mathrm{H} 2 \mathrm{O}}=234 \mathrm{mm} \mathrm{Hg} \times \frac{1.01325 \mathrm{bar}}{760 \mathrm{mm} \mathrm{Hg}}

= 0.312 bar

 Now according to the steam table  

With the vapour pressure of water as 0.312 bar the temperature corresponds to 70°C

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A chemist fills a reaction vessel with 7.92 atm nitrogen (N2) gas, 2.02 atm hydrogen (H2) gas, and 2.11 atm ammonia (NH3) gas at
djverab [1.8K]

<u>Answer:</u> The Gibbs free energy of the given reaction is -40 kJ

<u>Explanation:</u>

The given chemical equation follows:

N_2(g)+3H_2(g)\rightarrow 2NH_3(g)

The equation for the standard Gibbs free change of the above reaction is:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(NH_3(g))})]-[(1\times \Delta G^o_f_{(N_2(g))})+(3\times \Delta G^o_f_{(H_2(g))})]

We are given:

\Delta G^o_f_{(NH_3(l))}=-16.45kJ/mol\\\Delta G^o_f_{(H_2(g))}=0kJ/mol\\\Delta G^o_f_{(N_2(g))}=0kJ/mol

Putting values in above equation, we get:

\Delta G^o_{rxn}=[(2\times (-16.45))]-[(1\times (0))+(3\times (0))]\\\\\Delta G^o_{rxn}=-32.9kJ/mol

The equation used to Gibbs free energy of the reaction follows:

\Delta G=\Delta G^o+RT\ln Q_{eq}

where,

\Delta G = free energy of the reaction

\Delta G^o = standard Gibbs free energy = -32.9 kJ/mol = -32900 J/mol  (Conversion factor: 1 kJ = 1000 J)

R = Gas constant = 8.314J/K mol

T = Temperature = 25^oC=[273+25]K=298K

Q_{eq} = Ratio of concentration of products and reactants at any time = \frac{(p_{NH_3})^2}{(p_{H_2})^3\times p_{N_2}}

p_{NH_3}=2.11atm

p_{N_2}=7.92atm

p_{H_2}=2.02atm

Putting values in above equation, we get:

\Delta G=-32900J/mol+(8.314J/K.mol\times 298K\times \ln (\frac{(2.11)^2}{(2.02)^3\times 7.92}))\\\\\Delta G=-39553.04J/mol=--39.55kJ=-40kJ

Hence, the Gibbs free energy of the given reaction is -40 kJ

7 0
3 years ago
What is the water table?
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alexdok [17]

Answer:

c.

Explanation:

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When peroxide is swallowed, it generates oxygen bubbles in the stomach. Drinking higher concentrations of hydrogen peroxide can be very dangerous because it can cause tissue burns.
5 0
3 years ago
What is the molarity of 40ml of NaOH if it takes 25ml of 0.5 molar HCl to neutralize it?
Oksanka [162]

Answer:

Molarity of 40 ml of NaoH is 0.3125 mL

Explanation:

As we know  

Molarity of acid *  volume of acid = molarity of base * volume of base

Substituting the given values, we get  

0.5 * 25 = X* 40 \\X = \frac{0.5*25}{40} \\X = 0.3125

Molarity of 40 ml of NaoH is 0.3125 mL

6 0
3 years ago
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