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Rus_ich [418]
2 years ago
5

Calculate the work engergy gained or lost by the system when a gas expands from 35 to 55 l against a constant external presure o

f 3atm.
Chemistry
1 answer:
Mariana [72]2 years ago
6 0

Answer:  The work energy lost by the system is -6078 Joules

Explanation:

According to first law of thermodynamics:

\Delta E=q+w

\Delta E=Change in internal energy

q = heat absorbed or released

w = work done or by the system

w = work done by the system=-P\Delta V  {Work is done by the system as the final volume is greater than initial volume and is negative}

where P = pressure = 3 atm

\Delta V = change in volume = (55-35) L = 20 L

w =-3atm\times (20)L=-60Latm=-6078Joules  

{1Latm=101.3J}

Thus work energy lost by the system is -6078 Joules

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A sample of 28 Mg decays initially at a rate of 53500 disintegrations per minute, but the decay rate falls to 10980 disintegrati
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Answer : The half life of 28-Mg in hours is, 6.94

Explanation :

First we have to calculate the rate constant.

Expression for rate law for first order kinetics is given by:

k=\frac{2.303}{t}\log\frac{a}{a-x}

where,

k = rate constant

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a - x = amount left after decay process disintegrate = 53500 - 10980 = 42520

Now put all the given values in above equation, we get

k=\frac{2.303}{48.0}\log\frac{53500}{42520}

k=9.98\times 10^{-2}hr^{-1}

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k=\frac{0.693}{t_{1/2}}

9.98\times 10^{-2}=\frac{0.693}{t_{1/2}}

t_{1/2}=6.94hr

Therefore, the half life of 28-Mg in hours is, 6.94

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