Answer:
1) ΔG°r(298 K) = - 28.619 KJ/mol
2) ΔG°r will decrease with decreasing temperature
Explanation:
- CO(g) + H2O(g) → H2(g) + CO2(g)
1) ΔG°r = ∑νiΔG°f,i
⇒ ΔG°r(298 K) = ΔG°CO2(g) + ΔG°H2(g) - ΔG°H2O(g) - ΔG°CO(g)
from literature, T = 298 K:
∴ ΔG°CO2(g) = - 394.359 KJ/mol
∴ ΔG°CO(g) = - 137.152 KJ/mol
∴ ΔG°H2(g) = 0 KJ/mol........pure substance
∴ ΔG°H2O(g) = - 228.588 KJ/mol
⇒ ΔG°r(298 K) = - 394.359 KJ/mol + 0 KJ/mol - ( - 228.588 KJ/mol ) - ( - 137.152 KJ7mol )
⇒ ΔG°r(298 K) = - 28.619 KJ/mol
2) K = e∧(-ΔG°/RT)
∴ R = 8.314 E-3 KJ/K.mol
∴ T = 298 K
⇒ K = e∧(-28.619/(8.314 E-3)(298) = 9.624 E-6
⇒ ΔG°r = - RTLnK
If T (↓) ⇒ ΔG°r (↓)
assuming T = 200 K
⇒ ΔG°r(200 K) = - (8.314 E-3)(200)Ln(9.624E-3)
⇒ ΔG°r (200K) = - 19.207 KJ/mol < ΔG°r(298 K) = - 28.619 KJ/mol
Excess reactant : Na
NaCl produced : = 16.497 g
<h3>Further explanation</h3>
Given
Reaction(balanced)
2Na + Cl₂⇒ 2NaCl
20 g Na
10 g Cl₂
Required
Excess reactant
NaCl produced
Solution
mol Na(Ar = 23 g/mol) :
= 20 : 23 = 0.87
mol Cl₂(MW=71 g/mol):
= 10 : 71 g/mol = 0.141
mol : coefficient :
Na = 0.87 : 2 = 0.435
Cl₂ = 0.141 : 1 = 0.141
Limiting reactant : Cl₂(smaller ratio)
Excess reactant : Na
Mol NaCl based on mol Cl₂, so mol NaCl :
= 2/1 x mol Cl₂
= 2/1 x 0.141
= 0.282
Mass NaCl :
= 0.282 x 58.5 g/mol
= 16.497 g
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Answer:
The intermolecular forces between water molecules are stronger than those between oxygen molecules. In general, the bigger the molecule, the stronger the intermolecular forces, so the higher the melting and boiling points.
