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The branched structure isomer will require less energy to melt than the straight chain isomer
explanation
Branched structure isomer has weak intermolecular forces of attraction as compared to straight chain isomers. In addition the branched isomer has a low boiling point as compared to straight chain isomers. Since boiling require the of the intermolecular forces tend to have lower boiling point than straight chain
Answer:
0.2024 M
Explanation:
For the decomposition reactio given, let's do an equilibrium chart. Let's call the initial concentration of NH₃ as C:
2NH₃(g) ⇄ N₂(g) + 3H₂(g)
C 0 0 Initial
-2x +x +3x Reacts (stoichiometry is 1:1:3)
C - 2x x 3x Equilibrium
3x = 0.252
x = 0.084 M
The equilibrium constant (Kc) is the multiplication of the concentrations of the products elevated by their coefficients, divided by the multiplication of reactants concentrations elevated by their coefficients.
Kc = ([H₂]³*[N₂])/([NH₃]²)
4.50 = [(0.252)³*(0.084)]/(C - 2*0.084)²
4.50 = 0.00533/(C - 0.168)²
4.50 = 0.00533/(C² - 0.336C + 0.028224)
4.50C² - 1.512C + 0.127008 = 0.00533
4.50C² - 1.512C + 0.121678 = 0
Solving the equation by a graphic calculator, for C > 0.168
C = 0.2024 M
We are given the base dissociation constant, Kb, for Pyridine (C5H5N) which is 1.4x10^-9. The acid dissociation constant, Ka for the Pyridium ion or the conjugate acid of Pyridine is to be determined. We know from our chemistry classes that:
Kw = Kb * Ka
where Kw is always equal to 1x10^-14
so, to solve for Ka of Pyridium ion, substitute Kb to the equation together with Kw and solve for Ka:
1x10^-14 = 1.4x10^-9 * Ka
solve for Ka
Ka = 7.14x10^-6
Therefore, the acid dissociation constant of Pyridinium ion is 7.14x10^-6.
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Positive ion with a radius smaller than the radius of the atom
