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Nutka1998 [239]
3 years ago
8

What volume of so2 is produced at 325 k and 1.35 atm when 15.0 grams of hcl reacts with excess k2so3?

Chemistry
1 answer:
Helen [10]3 years ago
8 0
The balanced equation for the above reaction is as follows;
2HCl + K₂SO₃ ---> 2KCl + H₂O + SO₂
stoichiometry of HCl to SO₂ is 2:1
number of moles of HCl reacted - 15.0 g / 36.5 g/mol = 0.411 mol 
according to molar ratio 
number of SO₂ moles formed - 0.411 mol /2 = 0.206 mol
since we know the number of moles we can find volume using ideal gas law equation 
PV = nRT
where
 P - pressure - 1.35 atm x 101 325 Pa/atm = 136 789 Pa 
V - volume 
n - number of moles - 0.206 mol 
R - universal gas constant - 8.314 Jmol⁻¹K⁻¹
T - temperature - 325 K
substituting values in the equation 

136 789 Pa x V = 0.206 mol x 8.314 Jmol⁻¹K⁻¹ x 325 K 
V = 4.07 L 
volume of SO₂ formed is 4.07 L


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Answer:

K_2Cr_2O_7 (aq) + 14 HCl (aq) + 3 SnCl_2 (aq)\rightarrow 2 CrCl_3 (aq) + 7 H_2O (l) + 3 SnCl_4 (aq) + 2 KCl (aq)

Explanation:

The products of this reaction are given by:

K_2Cr_2O_7 (aq) + SnCl_2 (aq) + HCl (aq)\rightarrow KCl (aq) + SnCl_4 (aq) + CrCl_3 (aq) + H_2O (l)

Firstly, dichromate anion becomes chromium(III) cation, let's write this change:

Cr_2O_7^{2-} (aq)\rightarrow Cr^{3+} (aq)

The following steps should be taken:

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Cr_2O_7^{2-} (aq)\rightarrow 2 Cr^{3+} (aq)

  • balance oxygen atoms by adding 7 water molecules on the right:

Cr_2O_7^{2-} (aq)\rightarrow 2 Cr^{3+} (aq) + 7 H_2O (l)

  • balance the hydrogen atoms by adding 14 protons on the left:

Cr_2O_7^{2-} (aq) + 14 H^+ (aq)\rightarrow 2 Cr^{3+} (aq) + 7 H_2O (l)

  • balance the charge (the total net charge on the left is 12+, on the right we have 6+, so 6 electrons are needed on the left):

Cr_2O_7^{2-} (aq) + 14 H^+ (aq) + 6e^-\rightarrow 2 Cr^{3+} (aq) + 7 H_2O (l)

Similarly, tin(II) cation becomes tin(IV) cation:

Sn^{2+} (aq)\rightarrow Sn^{4+} (aq) + 2e^-

Now that we have the two half-equations, multiply the second one by 3, so that it also has 6 electrons that will be cancelled out upon addition of the two half-equations:

Cr_2O_7^{2-} (aq) + 14 H^+ (aq) + 6e^-\rightarrow 2 Cr^{3+} (aq) + 7 H_2O (l)

3 Sn^{2+} (aq)\rightarrow 3 Sn^{4+} (aq) + 6e^-

Add them together:

Cr_2O_7^{2-} (aq) + 14 H^+ (aq) + 3 Sn^{2+} (aq)\rightarrow 2 Cr^{3+} (aq) + 7 H_2O (l) + 3 Sn^{4+} (aq)

Adding the ions spectators:

K_2Cr_2O_7 (aq) + 14 HCl (aq) + 3 SnCl_2 (aq)\rightarrow 2 CrCl_3 (aq) + 7 H_2O (l) + 3 SnCl_4 (aq) + 2 KCl (aq)

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