Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
Answer:
- contains oxygen
- provides warmth
- blocks harmful energy from the Sun
Explanation:
The atmosphere is crucial when it comes to providing living conditions on Earth. The gases in the atmosphere manage to balance the things just about right, so that the life can thrive. The atmosphere has oxygen, the gas that is used by pretty much every organism to be able to function. With its greenhouse gases, the atmosphere manages to trap the heat inside, thus providing warmth to the Earth. The numerous layers of the atmosphere manage to block in big portion the harmful energy from the Sun, with a special accent on the ozone layer, a layer that manages to stop most of the UV radiation.
The answer is A- single bonds made by 1 atom to 3 other atoms within a molecule
Answer: 49.0 cm^3
Explanation:
1) formula: density = mass / volume
=> volume = mass / density
2) mass (given) = 54.6 g
3) density (given) = 1114 kg / m^3
conversion of units: 1114 kg/ m^3 * 1000 g/kg * 1 m^3 / (1,000,000 cm^3) = 1.114 g/cm^3
4) calculation:
volume = 54.6 g / 1.114 g/cm^3 = 49.0 cm^3
