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In a flame photometric analysis, salt solution is first vaporized using the heat of flame, followed by this electrons from valance shell gets excited from ground state to excited state. Followed by this de-excitation of electron bring backs electrons to ground state. This process is accompanied by emission of photon. The photon emitted is characteristic of an element, and number of photons emitted can be used for quantitative analysis.
<span>Following are the investigative question that you can answer by doing this experiment.
</span>1) What information can be obtained from the colour of flame?
2) <span>State the relationship between wavelength, frequency, and energy?
</span><span>3) Can you identify the metal present in unknown sample provided?
4) How will you identify amount of metal present in sample solution?
5) </span><span>Why do different chemicals emit light of different colour?</span><span>
</span>
Answer:
-255.4 kJ
Explanation:
The free energy of a reversible reaction can be calculated by:
ΔG = (ΔG° + RTlnQ)*n
Where R is the gas constant (8.314x10⁻³ kJ/mol.K), T is the temperature in K, n is the number of moles of the products (n =1), and Q is the reaction quotient, which is calculated based on the multiplication of partial pressures by the partial pressure of the products elevated by their coefficient divide by the multiplication of the partial pressure of the reactants elevated by their coefficients.
C₂H₂(g) + 2H₂(g) ⇄ C₂H₆(g)
Q = pC₂H₆/[pC₂H₂ * (pH₂)²]
Q = 0.261/[8.58*(3.06)²]
Q = 3.2487x10⁻³
ΔG = -241.2 + 8.314x10⁻³x298*ln(3.2487x10⁻³)
ΔG = -255.4 kJ
The number of Ml of C₅H₈ that can be made from 366 ml C₅H₁₂ is 314.7 ml of C₅H₈
<u><em>calculation</em></u>
step 1: write the equation for formation of C₅H₈
C₅H₁₂ → C₅H₈ + 2 H₂
Step 2: find the mass of C₅H₁₂
mass = density × volume
= 0.620 g/ml × 366 ml =226.92 g
Step 3: find moles Of C₅H₁₂
moles = mass÷ molar mass
from periodic table the molar mass of C₅H₁₂ = (12 x5) +( 1 x12) = 72 g/mol
moles = 226.92 g÷ 72 g/mol =3.152 moles
Step 4: use the mole ratio to determine the moles of C₅H₈
C₅H₁₂:C₅H₈ is 1:1 from equation above
Therefore the moles of C₅H₈ is also = 3.152 moles
Step 5: find the mass of C₅H₈
mass = moles x molar mass
from periodic table the molar mass of C₅H₈ = (12 x5) +( 1 x8) = 68 g/mol
= 3.152 moles x 68 g/mol = 214.34 g
Step 6: find Ml of C₅H₈
=mass / density
= 214.34 g/0.681 g/ml = 314.7 ml
