Answer:
a) pH = 4.213
b) % dis = 2 %
Explanation:
Ch3COONa → CH3COO- + Na+
CH3COOH ↔ CH3COO- + H3O+
∴ Ka = 1.8 E-5 = ([ CH3COO- ] * [ H3O+ ]) / [ CH3COOH ]
mass balance:
⇒ <em>C</em> CH3COOH + <em>C</em> CH3COONa = [ CH3COOH ] + [ CH3COO- ]
<em>∴ C </em>CH3COOH = 3.40 mM = 3.4 mmol/mL * ( mol/1000mmol)*(1000mL/L)
∴ <em>C</em> CH3COONa = 1.00 M = 1.00 mol/L = 1.00 mmol/mL
⇒ [ CH3COOH ] = 4.4 - [ CH3COO- ]
charge balance:
⇒ [ H3O+ ] + [ Na+ ] = [ CH3COO- ] + [ OH- ]....is negligible [ OH-], comes from water
⇒ [ CH3COO- ] = [ H3O+ ] + 1.00
⇒ Ka = (( [ H3O+ ] + 1 )* [ H3O+ ]) / ( 3.4 - [ H3O+])) = 1.8 E-5
⇒ [ H3O+ ]² + [ H3O+ ] = 6.12 E-5 - 1.8 E-5 [ H3O+ ]
⇒ [ H3O+ ]² + [ H3O+ ] - 6.12 E-5 = 0
⇒ [ H3O+ ] = 6.12 E-5 M
⇒ pH = - Log [ H3O+ ] = 4.213
b) (% dis)* mol acid = <em>C</em> CH3COOH = 3.4
∴ mol CH3COOH = 500*3.4 = 1700 mmol = 1.7 mol
⇒ % dis = 3.4 / 1.7 = 2 %
Mass of KNO₃ : = 40.643 g
<h3>Further explanation</h3>
Given
28.5 g of K₃PO₄
Required
Mass of KNO₃
Solution
Reaction(Balanced equation) :
2K₃PO₄ + 3 Ca(NO₃)₂ = Ca₃(PO₄)₂ + 6 KNO₃
mol K₃PO₄(MW=212,27 g/mol) :
= mass : MW
= 28.5 : 212,27 g/mol
= 0.134
Mol ratio of K₃PO₄ : KNO₃ = 2 : 6, so mol KNO₃ :
= 6/2 x mol K₃PO₄
= 6/2 x 0.134
= 0.402
Mass of KNO₃ :
= mol x MW KNO₃
= 0.402 x 101,1032 g/mol
= 40.643 g
Answer:
The conversion achieved for the first CSTR impeller is 0.382
Discrepancy = 0.188
Explanation:
The impeller divides the CSTR into 2 equal reactors of volume 500gal
Using V = FaoX/ (-ra)
500gal = Fao×Xa/[(KCao^2( 1 -X1)^2]
500gal = CaoVoX1/ KCao^2(1-X1)
500gal= 500gal × X1'/(1 - X1)^2
(1 -X1)^2 = X1
X1^2 - 3X1 + 1 = 0
X1= 0.382
Conversion achieved in the first CSTR is 0.382
Actual measured CSTR = 57% =57/100=0.57
Discrepancy in the conversions= 0.57 -0.383 =0.188
Answer is: <span>C. propanal.
1-propanol is primary alcohol. With weak oxidizing agent primary alcohol gives aldehyde and with strong oxidizing agent primary alcohol gives carbonic acid.
</span>Oxidation of 1-propanol with <span>Na</span>₂<span>Cr</span>₂<span>O</span>₇<span> and sulfuric acid</span><span> gives propanal and o</span><span>xidation with </span>chromic acid<span> gives </span>propionic acid<span>.</span>
