It might me b but I am not sure
The vapor pressure of water at 50ºC will be greater than that at 10ºC because of the added energy and thus greater movement of the water molecules. If one knows the ∆Hvap at a given temperature, one can calculate the vapor pressure at another temperature. This uses the Clausius-Clapeyron (sp?) equation. It turns out the vapor pressure of water at 10º is 9.2 mm Hg, and that at 50º is 92.5 mm Hg.
Answer: 996 mmHg
Explanation:
According to avogadro's law, 1 mole of every substance occupies 22.4 L at NTP, weighs equal to the molecular mass and contains avogadro's number
of particles.
According to the ideal gas equation:

P = Pressure of the gas = ?
V= Volume of the gas = 25.5 L
T= Temperature of the gas = 13°C = (273+13) K = 286K
R= Gas constant = 0.0821 atmL/K mol
n= moles of gas= 1.42
(760mmHg=1atm)
Thus pressure of this gas sample is 996 mm Hg.
PH scale is from 1 to 14 and indicates how acidic or basic a solution is. To find pH or pOH we need to know the H⁺ ion concentration or OH⁻ concentration.
pH can be calculated using the following equation;
pH = -log[H⁺]
the H⁺ concentration of the given acid is 1.0 x 10⁻⁴ M. substituting this we can find the pH
pH = -log[1x10⁻⁴]
pH = 4
answer is 1) 4