Explanation:
Method of prepration of sodium thiosulphate - definition
In the laboratory, this salt can be prepared by heating an aqueous solution of sodium sulphite with sulphur or by boiling aqueous NaOH and sulfur according to this equation:

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Reactants are what make up the product.
Calcium carbonate has the formula: CaCO3
From the periodic table:
mass of calcium = 40 grams
mass of carbon = 12 grams
mass of oxygen = 16 grams
Therefore,
molar mass of CaCO3 = 40 + 12 + 3(16) = 100 grams
molar mass of carbonate = 12 + 3(16) = 60 grams
One mole of calcium carbonate contains one mole of carbonate. Therefore, 100 grams of CaCO3 contains 60 grams of CO3.
If the 0.5376 grams of the unknown substance is CaCO3, then the amount of carbonate will be:
amount of carbonate = (0.5376*60) / 100 = 0.32256 grams
Based on the above calculations, the sample is not CaCO3