Which complex ion can exhibit geometric isomerism? Assume that M is the metal ion, A and B are ligands, and the geometry is octa
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Answer : The volume of will be, 514.11 ml
Explanation :
The balanced chemical reaction will be,
First we have to calculate the mass of in tablet.
Now we have to calculate the moles of .
Molar mass of = 1 + 12 + 3(16) = 61 g/mole
Now we have to calculate the moles of .
From the balanced chemical reaction, we conclude that
As, 1 mole of react to give 1 mole of
So, 0.0202 mole of react to give 0.0202 mole of
The moles of = 0.0202 mole
Now we have to calculate the volume of by using ideal gas equation.
where,
P = pressure of gas = 1.00 atm
V = volume of gas = ?
T = temperature of gas =
n = number of moles of gas = 0.0202 mole
R = gas constant = 0.0821 L.atm/mole.K
Now put all the given values in the ideal gas equation, we get :
Therefore, the volume of will be, 514.11 ml
The scheme is shown below, the steps involved are as follow,
Step one: Reduction:
The carbonyl group of given compound on reduction using Wolf Kishner reagent converts the carbonyl group into -CH₂- group.
Step two: Epoxidation:
The double bond present in starting compound when treated with m-CPBA (<span>meta-Chloroperoxybenzoic acid) gives corrsponding epoxide.
Step three: Reduction:
The epoxide is reduced to alcohol on treatment with Lithium Aluminium Hydride (LiAlH</span>₄)<span> followed by hydrolysis.
Step four: Oxidation:
The hydroxyl group (alcohol) is oxidized to carbonyl (ketonic group) using oxidizing agent Chromic acid (H</span>₂CrO₄).
Step one: Reduction:
The carbonyl group of given compound on reduction using Wolf Kishner reagent converts the carbonyl group into -CH₂- group.
Step two: Epoxidation:
The double bond present in starting compound when treated with m-CPBA (<span>meta-Chloroperoxybenzoic acid) gives corrsponding epoxide.
Step three: Reduction:
The epoxide is reduced to alcohol on treatment with Lithium Aluminium Hydride (LiAlH</span>₄)<span> followed by hydrolysis.
Step four: Oxidation:
The hydroxyl group (alcohol) is oxidized to carbonyl (ketonic group) using oxidizing agent Chromic acid (H</span>₂CrO₄).