Write down the reaction schemes including intermediate if any to show the preparation in aqueous solution for each of the stereo
isomers of [Pt (nh3)(no2)Cl2]
1 answer:
Answer:
<em>Scheme attached</em>
Explanation:
<em>Trans</em> effect is involved in this synthesis. As in the reactions of planer metal complexes, trans effect dominates the stereo-chemistry of the product.
<em>Trans</em> effect
The role of the element present in trans position to the element to be substituted is called the trans effect. The nature of the ligand in trans position effects the substitution, if it has high <em>trans</em> effect it make the substitution difficult.
So when we attach NH₃ first to the ligand it make the trans substitution difficult, hence <em>cis</em> product will be formed.
As NO₂ has very low <em>trans</em> effect, so it doesn't effect the substitution and the <em>trans</em> product will be formed as usual.
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Answer:
11.39
Explanation:
Given that:
Given that:
Mass = 1.805 g
Molar mass = 82.0343 g/mol
The formula for the calculation of moles is shown below:
Thus,
Given Volume = 55 mL = 0.055 L ( 1 mL = 0.001 L)
Concentration = 0.4 M
Consider the ICE take for the dissociation of the base as:
B + H₂O ⇄ BH⁺ + OH⁻
At t=0 0.4 - -
At t =equilibrium (0.4-x) x x
The expression for dissociation constant is:
x is very small, so (0.4 - x) ≅ 0.4
Solving for x, we get:
x = 2.4606×10⁻³ M
pOH = -log[OH⁻] = -log(2.4606×10⁻³) = 2.61
<u>pH = 14 - pOH = 14 - 2.61 = 11.39</u>