Answer:
when it reduces heat.
Explanation:
Thermal energy is transferred to material,the motion of its particles speeds up and it's temperature differences.Insulating materials are bad conductors and so this reduces the heat loss by conduction.The material also prevents air circulating inside the cavity,therefore reducing heat loss by convection.Heat loss through the roof can be reduced by laying loft insulation.
Lowery-Bronsted theory is applied here. Acc. to this theory Base accepts protons and Acids donate proton.
Part 1:
Aniline is less basic than ethylamine because the lone pair on nitrogen (which accepts proton) is not localized. It resonates throughout the conjugated system of phenyl ring. Hence due to unavailability of electrons for accepting proton it is less basic compare to ethylamine. In ethyl amine the lone pair of electron is localized and available to abstract proton.
Part 2:
In this case the alkyl groups attached to -NH₂ (in ethylamine) and -O⁻ (in ethoxide are same (i.e. CH₃-CH₂-). Ethoxide is more basic than ethylamine because ethoxide is a conjugate base of ethanol (pKa value of ethanol = 15.9 very weak acid) and the conjugate base of weak acid is always a strong base. Secondly, the oxygen atom more Electronegative than Nitrogen atom can attract more electron cloud from alkyl group as compared to Nitrogen in ethylamine. Hence, oxygen in ethoxide attains greater electron cloud than the nitrogen in ethylamine. Therefore, it is more basic than ethylamine.
This is an acid base reaction and the chemical equation for the above reaction is as follows;
KOH + HClO₄ ---> KClO₄ + H₂O
the stoichiometry of acid to base is 1:1
KOH is a strong base and HClO₄ is a strong acid therefore they both ionize completely into their respective ions
Number of KOH moles - 0.723 M/1000 mL/L x 25.0 mL = 0.018 mol
Number of HClO₄ moles - 0.273 M/1000 mL/L x 50 mL = 0.013 mol
since acid and base react completely, 0.013 mol of acid reacts with 0.013 mol of base.
The excess base remaining is - 0.018 - 0.013 = 0.005 mol
total volume of solution = 25.0 mL + 50.0 mL = 75.0 mL
[OH⁻] = 0.005 mol/0.075 L = 0.067 M
pOH = -log[OH⁻]
pOH = -log(0.067 M)
pOH = 1.17
pOH + pH = 14
Therefore pH = 14 - 1.17 = 12.83
by knowing pH we can calculate the [H₃O⁺]
pH = -log [H₃O⁺]
[H₃O⁺] = antilog[-12.83]
[H₃O⁺]= 1.47 x 10⁻¹³ M
An energy diagram of a chemical reactions illustrates the changes of energy as the chemical reactions advances.
At first, the energy in the diagram is the energy of the reactants.
As the reaction goes forward, the reactants start to react forming a transition compound, with a maximum energy level on the graph. This is the hill. So the hill represents the Activation Energy.
After that, the energy starts to decrease and at the end you have the energy of the products, which may be higher or lower than the initial energy of the reactants, depending upon whether the reaction is exothermic or endothermic.
For exothermic reactions the energy level of the products is lower than the energy level of the reactants, while for endothermic reactions the energy level of the products is higher than the energy level of the reactants.
Answer:
1. 1.8 mol or the 2 one (B)
Explanation: