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Answer:
The barrier has to be 34.23 kJ/mol lower when the sucrose is in the active site of the enzyme
Explanation:
From the given information:
The activation barrier for the hydrolysis of sucrose into glucose and fructose is 108 kJ/mol.
In this same concentration for the glucose and fructose; the reaction rate can be calculated by the rate factor which can be illustrated from the Arrhenius equation;
Rate factor in the absence of catalyst:
Rate factor in the presence of catalyst:
Assuming the catalyzed reaction and the uncatalyzed reaction are taking place at the same temperature :
Then;
the ratio of the rate factors can be expressed as:
Thus;
Let say the assumed temperature = 25° C
= (25+ 273)K
= 298 K
Then ;
The barrier has to be 34.23 kJ/mol lower when the sucrose is in the active site of the enzyme
The elements of same group are placed in same group as they have similar properties. So Calcium is the element which resembles Mangesium.
Calcium and Magnesium both are alkaline earth metals.
They have similar properties as they have similar outer or valence shell electronic configuration
The general electronic configuration of alkaline earht metal is ns2
The electronic configuration of Mg [atomic number 12] and Ca [atomic number 20] are
and
respectively.