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Sliva [168]
3 years ago
8

A sailor on a trans-Pacific solo voyage notices one day that if he puts 375. mL of fresh water into a plastic cup fresh water we

ighing 15.0 g, the cup floats in the seawater around his boat with the fresh water inside the cup at exactly the same level as the seawater outside the cup.
Required:
Calculate the amount of salt dissolved in each liter of seawater.
Chemistry
1 answer:
ElenaW [278]3 years ago
3 0

Answer:

Amount of salt dissolved in each liter of seawater = 40 g

Explanation:

According to Archimedes principle, a body will float in a fluid if the upthrust experienced by a body is equal to the to the weight of the body.

Also, the volume of seawater displaced equals the volume of freshwater in the cup.

From the above principle, since the freshwater and cup floats in the seawater, their combined weight equals the upthrust.

Therefore, mass of equal volume of displaced seawater = mass of freshwater + mass of cup

Mass of freshwater = density of freshwater * volume

density of freshwater = 1 g/mL; volume = 375 mL

mass of freshwater = 375 mL * 1 g/mL = 375 g

mass of seawater = 375 + 15 = 390 g

mass of salt in 375 mL seawater = mass of seawater - mass of freshwater

mass of salt = (390 - 375) g = 15 g

Since 15 g of salt are dissolved in 375 mL seawater, mass of salt in 1 L of seawater =(1000 mL/ 375) * 15g = 40 g

Therefore, amount of salt dissolved in each liter of seawater = 40 g

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Assuming complete dissociation of the solute, how many grams of KNO3 must be added to 275 mL of water to produce a solution that
iragen [17]

Answer:

108.43 grams KNO₃

Explanation:

To solve this problem we use the formula:

  • ΔT = Kf * b * i

Where

  • ΔT is the temperature difference (14.5 K)
  • Kf is the cryoscopic constant (1.86 K·m⁻¹)
  • b is the molality of the solution (moles KNO₃ per kg of water)
  • and<em> i</em> is the van't Hoff factor (2 for KNO₃)

We <u>solve for b</u>:

  • 14.5 K = 1.86 K·m⁻¹ * b * 2
  • b = 3.90 m

Using the given volume of water and its density (aprx. 1 g/mL) we <u>calculate the necessary moles of KNO₃</u>:

  • 275 mL water ≅ 275 g water
  • 275 g /1000 = 0.275 kg
  • moles KNO₃ = molality * kg water = 3.90 * 0.275
  • moles KNO₃ = 1.0725 moles KNO₃

Finally we <u>convert KNO₃ moles to grams</u>, using its molecular weight:

  • 1.0725 moles KNO₃ * 101.103 g/mol = 108.43 grams KNO₃
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2 years ago
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