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AleksandrR [38]
3 years ago
9

Find the pH of a 0.100 molar H2C6O6 solution with ka, where KA is equal 8.0×10–5​

Chemistry
1 answer:
lubasha [3.4K]3 years ago
4 0

The pH of the solution is 2.54.

Explanation:

pH is the measure of acidity of the solution and Ka is the dissociation constant. Dissociation constant is the measure of concentration of hydrogen ion donated to the solution.

The solution of C₆H₂O₆ will get dissociated as C₆HO₆ and H+ ions. So the molar concentration of 0.1 M is present at the initial stage. Lets consider that the concentration of hydrogen ion released as x and the same amount of the base ion will also be released.

So the dissociation constant Kₐ can be written as the ratio of concentration of products to the concentration of reactants. As the concentration of reactants is given as 0.1 M and the concentration of products is considered as x for both hydrogen and base ion. Then the

K_{a}=\frac{[H^{+}][HB] }{[reactant]}

[HB] is the concentration of base.

8 * 10^{-5} =\frac{x^{2}  }{0.1}\\\\\\x^{2} = 8 * 10^{-5}*0.1

x^{2} = 0.08 * 10^{-4}\\ \\x = 0.283*10^{-2}

Then

pH = - log [x] = - log [ 0.283 * 10^{-2}]\\ \\pH = 2 + 0.548 = 2.54

So the pH of the solution is 2.54.

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Determine the percent composition by mass of a 100g salt solution which contains 20g salt
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Mass of solution=100g

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Automobile airbags contain solid sodium azide, NaN3, that reacts to produce nitrogen gas when heated, thus inflating the bag. 2N
Vitek1552 [10]

Answer : The value of work done for the system is 1144.69 J

Explanation :

First we have to calculate the moles of NaN_3

\text{Moles of }NaN_3=\frac{\text{Mass of }NaN_3}{\text{Molar mass of }NaN_3}

Molar mass of NaN_3 = 65.01 g/mole

\text{Moles of }NaN_3=\frac{20.2g}{65.01g/mole}=0.311mole

Now we have to calculate the moles of nitrogen gas.

The balanced chemical reaction is,

2NaN_3(s)\rightarrow 2Na(s)+3N_2(g)

From the balanced reaction we conclude that

As, 2 mole of NaN_3 react to give 3 mole of N_2

So, 0.311 moles of NaN_3 react to give \frac{0.311}{2}\times 3=0.466 moles of N_2

Now we have to calculate the volume of nitrogen gas.

Using ideal gas equation:

PV=nRT

where,

P = Pressure of N_2 gas = 1.00 atm

V = Volume of N_2 gas = ?

n = number of moles N_2 = 0.466 mole

R = Gas constant = 0.0821L.atm/mol.K

T = Temperature of N_2 gas = 22^oC=273+22=295K

Putting values in above equation, we get:

1.00atm\times V=0.466mole\times (0.0821L.atm/mol.K)\times 295K

V=11.3L

As initially no nitrogen was present. So,

Volume expanded = Volume of nitrogen evolved

Thus,

Expansion work = Pressure × Volume

Expansion work = 1.00 atm × 11.3 L

Expansion work = 11.3 L.atm

Conversion used : (1 L.atm = 101.3 J)

Expansion work = 11.3 × 101.3 = 1144.69 J

Therefore, the value of work done for the system is 1144.69 J

5 0
3 years ago
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