A 248-g piece of copper is dropped into 390 mL of water at 22.6 °C. The final temperature of the water was measured as 39.9 °C.
1 answer:
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Answer:
To determine the enthalpy and entropy of dissolving a compound, you need to measure the Ksp at multiple temperatures. Then, plot ln(Ksp) vs. 1/T. The slope of the plotted line relates to the enthalpy (ΔH) of dissolving and the intercept of the plotted line relates to the entropy (ΔS) of dissolving.
Explanation:
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In this case, according to the given information, it turns out possible for us use the thermodynamic definition of the Gibbs free energy and its relationship with Ksp as follows:
Thus, by combining them, we obtain:
Which is related to the general line equation:
Whereas:
It means that we answer to the blanks as follows:
To determine the enthalpy and entropy of dissolving a compound, you need to measure the Ksp at multiple temperatures. Then, plot ln(Ksp) vs. 1/T. The slope of the plotted line relates to the enthalpy (ΔH) of dissolving and the intercept of the plotted line relates to the entropy (ΔS) of dissolving.
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