So we have Barium nitrate with a solubility of 8.7g in 100g water at 20°C.
using that relation
i.e.
8.7g (barium nitrate) =100g (water)
1g barium nitrate = 100/8.7 g water
27g barium nitrate = (100/ 8.7 ) × 27
= 310.34 g
therefore,
you need 310.34g of water is in the jar.
Answer:
32.04°C will be the final temperature of the solution.
Explanation:
Moles of potassium chloride = 0.200 mol
MAs sof KCl= 0.200 mol × 74.5 g/mol= 14.9 g
Enthalpy of solvation of potassium nitrate =
Energy released when 0.200 moles of KCl is dissolved in water = Q
(1 kJ = 1000 J)
Heat released on dissolving 0.200 moles of KCl is equal to heat absorbed by water = Q
Mass of solution , m= 80.0 g +14.9 g = 94.9 g
Specific heat of water = c = 4.184 J/g°C
Initial temperature of the water =
Final temperature of the water =
32.04°C will be the final temperature of the solution.
Answer:
The minimum molecular weight of the enzyme is 29.82 g/mol
Explanation:
<u>Step 1:</u> Given data
The volume of the solution = 10 ml = 10*10^-3L
Molarity of the solution = 1.3 mg/ml
moles of AgNO3 added = 0.436 µmol = 0.436 * 10^-3 mmol
<u>Step 2:</u> Calculate the mass
Density = mass/ volume
1.3mg/mL = mass/ 10.0 mL
mass = 1.3mg/mL *10.0 mL = 13mg
<u>Step 3:</u> Calculate minimum molecular weight
Molecular weight = mass of the enzyme / number of moles
Molecular weight of the enzyme = 13mg/ 0.436 * 10^-3 mmol
Molecular weight = 29.82 g/mole
The minimum molecular weight of the enzyme is 29.82 g/mol
Answer:The product formed on reaction with hydroxide ion as nucleophile is 2R-hexane-2-ol.
The product formed on reaction with water would be a 50:50 mixture of
2S-hexane-2-ol. and 2R-hexane-2-ol.
Explanation:
2S-iodohexane on reactiong with hydroxide ion would undergo SN² substitution reaction that is substitution bimolecular. Hydroxide ion has a negative charge and hence it is a quite good nucleophile .
The rate of a SN² reaction depends on both the substrate and nucleophile . Here the substrate is a secondary carbon center having Iodine as a leaving group.SN² reaction takes place here as hydroxide ion is a good nucleophile and it can attack the secondary carbon center from the back side leading to the formation of 2R-hexane-2-ol.
In a SN² reaction since the the nucleophile attacks from the back-side so the product formation takes place with the inversion of configuration.
When the same substrate S-2-iodohexane undergoes a substitution reaction with water as a nucleophile then the reaction occurs through (SN¹) substitution nucleophilic unimolecular mechanism .
The rate of a SN¹ reaction depends only on the nature of substrate and is independent of the nature of nucleophile.
The SN¹ reaction is a 2 step reaction , in the first step leaving group leaves leading to the formation of a carbocation and once the carbocation is formed then any weaker nucleophile or even solvent molecules can attack leading the formation of products.
In this case a secondary carbocation would be generated in the first step and then water will attack this carbocation to form the product in the second step.
The product formed on using water as a nucleophile would be a racemic mixture of R and S isomers of hexane -2-ol in 50:50 ratio. The two products formed would be 2R-hexane-2-ol and 2S-hexane-2-ol.
Kindly refer the attachment for reaction mechanism and structure of products.