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Reptile [31]
3 years ago
5

A tire at 21ÁC has a pressure of 0.82 atm. Its temperature decreases to _3.5ÁC. If there is no volume change in the tire, what i

s the pressure after the temperature change?
Chemistry
1 answer:
amid [387]3 years ago
3 0
Volumen = constant => P/T = constant

T1 = 21°C + 273.15 = 294.15 k
P1 = 0.82 atm

T2 = - 3.5°C + 273.15 = 269.65 k
P2 = ?

P2 / 269.65k = 0.82atm / 294.15k

P2 = [0.82atm / 294.15k] * 269.65kg = 0.75 atm
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Be sure to answer all parts.The equilibrium constant, Kc, for the formation of nitrosyl chloride from nitric oxide and chlorine,
djverab [1.8K]

<u>Answer:</u> The reaction proceeds in the forward direction

<u>Explanation:</u>

For the given chemical equation:

2NO(g)+Cl_2(g)\rightleftharpoons 2NOCl(g)

Relation of K_p\text{ with }K_c is given by the formula:

K_p=K_c(RT)^{\Delta n_g}

where,

K_p = equilibrium constant in terms of partial pressure = ?

K_c = equilibrium constant in terms of concentration = 6.5\times 10^4

R = Gas constant = 0.0821\text{ L atm }mol^{-1}K^{-1}

T = temperature = 35^oC=[35+273]K=308K

\Delta n_g = change in number of moles of gas particles = n_{products}-n_{reactants}=2-3=-1

Putting values in above equation, we get:

K_p=6.5\times 10^4\times (0.0821\times 500)^{-1}\\\\K_p=1583.43

K_p is the constant of a certain reaction at equilibrium while Q_p is the quotient of activities of products and reactants at any stage other than equilibrium of a reaction.

The expression of Q_p for above equation follows:

Q_p=\frac{(p_{NOCl})^2}{p_{Cl_2}\times (p_{NO})^2}

We are given:

p_{NOCl}=1.76atm

p_{NO}=1.01atm

p_{Cl_2}=0.42atm

Putting values in above equation, we get:

Q_p=\frac{(1.76)^2}{0.42\times (1.01)^2}=7.23

We are given:

K_p=1583.43

There are 3 conditions:

  • When K_{p}>Q_p; the reaction is product favored.
  • When K_{p}; the reaction is reactant favored.
  • When K_{p}=Q_p; the reaction is in equilibrium

As, K_p>Q_p, the reaction will be favoring product side.

Hence, the reaction proceeds in the forward direction

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