Answer : The correct option is, +91 kJ/mole
Solution :
The balanced cell reaction will be,

Here copper (Cu) undergoes oxidation by loss of electrons, thus act as anode. Lead (Pb) undergoes reduction by gain of electrons and thus act as cathode.
First we have to calculate the standard electrode potential of the cell.
![E^0_{[Pb^{2+}/Pb]}=-0.13V](https://tex.z-dn.net/?f=E%5E0_%7B%5BPb%5E%7B2%2B%7D%2FPb%5D%7D%3D-0.13V)
![E^0_{[Cu^{2+}/Cu]}=+0.34V](https://tex.z-dn.net/?f=E%5E0_%7B%5BCu%5E%7B2%2B%7D%2FCu%5D%7D%3D%2B0.34V)

![E^0_{cell}=E^0_{[Pb^{2+}/Pb]}-E^0_{[Cu^{2+}/Cu]}](https://tex.z-dn.net/?f=E%5E0_%7Bcell%7D%3DE%5E0_%7B%5BPb%5E%7B2%2B%7D%2FPb%5D%7D-E%5E0_%7B%5BCu%5E%7B2%2B%7D%2FCu%5D%7D)

Now we have to calculate the standard Gibbs free energy.
Formula used :

where,
= standard Gibbs free energy = ?
n = number of electrons = 2
F = Faraday constant = 96500 C/mole
= standard e.m.f of cell = -0.47 V
Now put all the given values in this formula, we get the Gibbs free energy.

Therefore, the standard Gibbs free energy is +91 kJ/mole
Mass of sodium :- 23 grams
Mass of Chlorine :- 35.5 grams
Mass of NaCl :- 58.5 grams
mass given :- 25 grams
moles :- 0.432 ( given mass/ ionic mass)

Actually, there are four kinds of reptile motion:
Concertina - vermiform. Circular muscles around the snake squeeze the front of the snake's body out long, then the latter half is pulled forward.
Rectilinear crawling - Belly scutes are moved forward individually in a wave-like motion.
Side-winding - Snake's version of "walking". Use by several species to move over fluidic substrates, such as sand.
Lateral undulation - Most common form of movement. Snake presses on alternating pressure points to force body forward (or backward)
(taken from a user on Yahoo from Correct Answers)
No, they do not. Hope I helped! :)
It shows the type of atoms/elements in a substance
Different types of atoms have different emission spectrum - a concept supported by Bohr quantum theory - hence one is able to identify elements in a substance using a method called spectroscopy.
Explanation:
When an electron jumps from a low energy orbital to a higher energy orbital in an atom, it absorbs a specific wavelength of electromagnetic radiation (This is called absorption spectrum). Vice versa, if the same electron jumps from a higher to a lower energy orbital it releases the equivalent quantum energy in electromagnetic wave (This is called emission spectrum). Different types of atoms of different elements have a unique spectrum identifier.
Learn More:
Learn more about spectroscopy;
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