Total vapor pressure can be calculated using partial vapor pressures and mole fraction as follows:

Here,
is mole fraction of A,
is mole fraction of B,
is partial pressure of A and
is partial pressure of B.
The mole fraction of A and B are related to each other as follows:

In this problem, A is hexane and B is octane, mole fraction of hexane is given 0.580 thus, mole fraction of octane can be calculated as follows:

Partial pressure of hexane and octane is given 183 mmHg and 59.2 mmHg respectively.
Now, vapor pressure can be calculated as follows:

Putting the values,

Therefore, total vapor pressure over the solution of hexane and octane is 131 mmHg.
The amount of the solute is constant during dilution. So the mole number of HCl is 2*1.5=3 mole. The volume of HCl stock is 3/12=0.25 L. So using 0.25 L stock solution and dilute to 2.0 L.
3.21e+11 is your answer for 321 millimeters in picometers. Hope this helps!