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Alenkinab [10]
3 years ago
12

Calculate the concentration of hydronium and hydroxide ions in a 0.050 M solution of nitric acid.

Chemistry
1 answer:
Mazyrski [523]3 years ago
3 0

Answer:

[H₃O⁺] = 0.05 M & [OH⁻] = 2.0 x 10⁻¹³.

Explanation:

  • HNO₃ is completely ionized in water as:

<em>HNO₃ + H₂O → H₃O⁺ + NO₃⁻.</em>

  • The concentration of hydronium ion is equal to the concentration of HNO₃:

[H₃O⁺] = 0.05 M.

∵ [H₃O⁺][OH⁻] = 10⁻¹⁴.

<em>∴ [OH⁻] = 10⁻¹⁴/[H₃O⁺] </em>= 10⁻¹⁴/0.05 = <em>2.0 x 10⁻¹³.</em>

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Air at 25°C with a dew point of 10 °C enters a humidifier. The air leaving the unit has an absolute humidity of 0.07 kg of water
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Explanation:

The given data is as follows.

         Temperature of dry bulb of air = 25^{o}C

          Dew point = 10^{o}C = (10 + 273) K = 283 K

At the dew point temperature, the first drop of water condenses out of air and then,

        Partial pressure of water vapor (P_{a}) = vapor pressure of water at a given temperature (P^{s}_{a})

Using Antoine's equation we get the following.

            ln (P^{s}_{a}) = 16.26205 - \frac{3799.887}{T(K) - 46.854}

            ln (P^{s}_{a}) = 16.26205 - \frac{3799.887}{283 - 46.854}

                               = 0.17079

                   P^{s}_{a} = 1.18624 kPa

As total pressure (P_{t}) = atmospheric pressure = 760 mm Hg

                                   = 101..325 kPa

The absolute humidity of inlet air = \frac{P^{s}_{a}}{P_{t} - P^{s}_{a}} \times \frac{18 kg H_{2}O}{29 \text{kg dry air}}

                  \frac{1.18624}{101.325 - 1.18624} \times \frac{18 kg H_{2}O}{29 \text{kg dry air}}

                 = 0.00735 kg H_{2}O/ kg dry air

Hence, air leaving the humidifier has a has an absolute humidity (%) of 0.07 kg H_{2}O/ kg dry air.

Therefore, amount of water evaporated for every 1 kg dry air entering the humidifier is as follows.

                 0.07 kg - 0.00735 kg

              = 0.06265 kg H_{2}O for every 1 kg dry air

Hence, calculate the amount of water evaporated for every 100 kg of dry air as follows.

                0.06265 kg \times 100

                  = 6.265 kg

Thus, we can conclude that kg of water the must be evaporated into the air for every 100 kg of dry air entering the unit is 6.265 kg.

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