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kumpel [21]
3 years ago
12

A phosphate buffer solution (25.00 mL sample) used for a growth medium was titrated with 0.1000 M hydrochloric acid. The compone

nts of the buffer were sodium monohydrogenphosphate and sodium dihydrogenphosphate. The first endpoint occurred at a volume of 10.32 mL, and the second occurred after an additional 18.62 mL was added, for a total volume of 28.94 mL. What was the total concentration of phosphate (in any form) in the buffer?
Chemistry
1 answer:
AysviL [449]3 years ago
7 0

Answer:

0,07448M of phosphate buffer

Explanation:

sodium monohydrogenphosphate (Na₂HP) and sodium dihydrogenphosphate (NaH₂P) react with HCl thus:

Na₂HP + HCl ⇄ NaH₂P + NaCl <em>(1)</em>

NaH₂P + HCl ⇄ H₃P + NaCl <em>(2)</em>

The first endpoint is due the reaction (1), When all phosphate buffer is as NaH₂P form, begins the second reaction. That means that the second endpoint is due the total concentration of phosphate that is obtained thus:

0,01862L of HCl×\frac{0,1000mol}{L}= 1,862x10⁻³moles of HCl ≡ moles of phosphate buffer.

The concentration is:

\frac{1,862x10^{-3}moles}{0,02500L} = <em>0,07448M of phosphate buffer</em>

<em></em>

I hope it helps!

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Eduardwww [97]

Answer:

Moles of potassium chlorate reacted = 0.2529 moles

The amount of oxygen gas collected will be 12.8675 g

Explanation:

(a)

We are given:

Vapor pressure of water = 17.5 mmHg

Total vapor pressure = 748 mmHg

Vapor pressure of Oxygen gas = Total vapor pressure - Vapor pressure of water = (748 - 17.5) mmHg = 730.5 mmHg

To calculate the amount of Oxygen gas collected, we use the equation given by ideal gas which follows:

PV=nRT

where,

P = pressure of the gas = 730.5 mmHg  

V = Volume of the gas = 9.49 L

T = Temperature of the gas = 20^oC=[20+273]K=293K

R = Gas constant = 62.3637\text{ L.mmHg }mol^{-1}K^{-1}

n = number of moles of oxygen gas = ?

Putting values in above equation, we get:

730.5mmHg\times 9.49L=n\times 62.3637\text{ L.mmHg }mol^{-1}K^{-1}\times 293K\\\\n=\frac{730.5\times 9.49}{62.3637\times 293}=0.3794mol

According to the reaction shown below as:-

2KClO_3(s)\rightarrow 2KCl(s) +3O_2(g)

3 moles of oxygen gas are produced when 2 moles of potassium chlorate undergoes reaction.

So,

0.3794 mol of oxygen gas are produced when \frac{2}{3}\times 0.3794 moles of potassium chlorate undergoes reaction.

<u>Moles of potassium chlorate reacted = 0.2529 moles</u>

(b)

We are given:

Vapor pressure of water = 17.5 mmHg

Total vapor pressure = 753 mmHg

Vapor pressure of Oxygen gas = Total vapor pressure - Vapor pressure of water = (753 - 17.5) mmHg = 735.5 mmHg

To calculate the amount of Oxygen gas collected, we use the equation given by ideal gas which follows:

PV=nRT

where,

P = pressure of the gas = 735.5 mmHg  

V = Volume of the gas = 9.99 L

T = Temperature of the gas = 20^oC=[20+273]K=293K

R = Gas constant = 62.3637\text{ L.mmHg }mol^{-1}K^{-1}

n = number of moles of oxygen gas = ?

Putting values in above equation, we get:

735.5mmHg\times 9.99L=n\times 62.3637\text{ L.mmHg }mol^{-1}K^{-1}\times 293K\\\\n=\frac{735.5\times 9.99}{62.3637\times 293}=0.40211mol

Moles of Oxygen gas = 0.40211 moles

Molar mass of Oxygen gas = 32 g/mol

Putting values in above equation, we get:

0.037mol=\frac{\text{Mass of Oxygen gas}}{2g/mol}\\\\\text{Mass of Oxygen gas}=(0.40211mol\times 32g/mol)=12.8675g

<u>Hence, the amount of oxygen gas collected will be 12.8675 g</u>

5 0
2 years ago
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