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scoray [572]
3 years ago
11

The solubility of calcium oxalate, CaC2O4, in pure water is 4.8 × 10‑5 moles per liter. Cal­culate the value of Ksp for silver c

arbonate from this data.
Chemistry
1 answer:
inn [45]3 years ago
4 0

Answer:

2.3 × 10⁻⁹

Explanation:

Step 1: Write the reaction for the solution of calcium oxalate

CaC₂O₄(s) ⇄ Ca²⁺(aq) + C₂O₄²⁻(aq)

Step 2: Make an ICE chart

We can relate the molar solubility (S) with the solubility product constant (Ksp) through an ICE chart.

        CaC₂O₄(s) ⇄ Ca²⁺(aq) + C₂O₄²⁻(aq)

I                                0                 0

C                              +S               +S

E                                S                 S

The solubility product constant is:

Ksp = [Ca²⁺] × [C₂O₄²⁻] = S² = (4.8 × 10⁻⁵)² = 2.3 × 10⁻⁹

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A 50-mL volumetric cylinder with 0.1-mL accuracy scale should be used for this purpose since three significant figures of accuracy are required.

Explanation:

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A 50-mL volumetric cylinder with 0.1-mL accuracy scale should be used for this purpose since three significant figures of accuracy are required.

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6 0
3 years ago
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Un globo lleno de helio tenia un volumen de 8.5 L en el suelo a 20°C y a una presión de 750 torr. Cuando se le soltó, el globo s
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Answer:

El volumen del gas era 12.95 L

Explanation:

Se relaciona la presión y el volumen mediante la ley de Boyle, que dice:

“El volumen ocupado por una determinada masa gaseosa a temperatura constante, es inversamente proporcional a la presión”

La ley de Boyle se expresa matemáticamente como:  P*V=k

Por otro lado, la Ley de Charles consiste en la relación que existe entre el volumen y la temperatura absoluta de una cierta cantidad de gas ideal, el cual se mantiene a una presión constante. Esta ley dice que cuando la cantidad de gas y de presión se mantienen constantes, el cociente que existe entre el volumen y la temperatura siempre tendrán el mismo valor:  

\frac{V}{T}=k

Por último, la Ley de Gay Lussac dice que la temperatura absoluta y la presión son directamente proporcionales. Es decir, cuando se mantiene todo lo demás constante, mientras suba la temperatura de un gas subirá también su presión. Y mientras la temperatura del gas baje, lo mismo ocurrirá con la presión:

\frac{P}{T}=k

Combinado las mencionadas tres leyes se obtiene:

\frac{P*V}{T} =k

Cuando se desean estudiar dos diferentes estados, uno inicial y una final de un gas, se puede aplicar:

\frac{P1*V1}{T1} =\frac{P2*V2}{T2}

Recordando que la temperatura debe usarse en grados Kelvin, conoces los siguientes datos:

  • P1: 750 torr
  • V1: 8.5 L
  • T1: 20°C= 293°K (siendo 0°C=273°K)
  • P2: 425 torr
  • V2: ?
  • T2: -20°C= 253 °K

Reemplazando:

\frac{750 torr*8.5 L}{293K} =\frac{425 torr*V2}{253 K}

Resolviendo:

V2=\frac{750 torr*8.5 L}{293K} *\frac{253 K}{425 torr}

V2= 12.95 L

<u><em>El volumen del gas era 12.95 L</em></u>

<u><em></em></u>

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