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stealth61 [152]
3 years ago
9

A 150.0 mL sample of an aqueous solution at 25°C contains 15.2 mg of an unknown nonelectrolyte compound. If the solution has an

osmotic pressure of 8.44 torr, what is the molar mass of the unknown compound?294 g/mol223 g/mol195 g/mol448 g/mol341 g/mo
Chemistry
1 answer:
inysia [295]3 years ago
5 0

<u>Answer:</u> The molar mass of the unknown compound is 223.2 g/mol

<u>Explanation:</u>

To calculate the concentration of solute, we use the equation for osmotic pressure, which is:

\pi=iMRT

where,

\pi = osmotic pressure of the solution = 8.44 torr

i = Van't hoff factor = 1 (for non-electrolytes)

M = molarity of solute = ?

R = Gas constant = 62.3637\text{ L torr }mol^{-1}K^{-1}

T = temperature of the solution = 25^oC=[273+25]=298K

Putting values in above equation, we get:

8.44torr=1\times M\times 62.3637\text{ L. torr }mol^{-1}K^{-1}\times 298K\\\\M=\frac{8.44}{1\times 62.3637\times 298}=4.54\times 10^{-4}M

To calculate the molecular mass of solute, we use the equation used to calculate the molarity of solution:

\text{Molarity of the solution}=\frac{\text{Mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (in mL)}}

We are given:

Molarity of solution = 4.54\times 10^{-4}M

Given mass of unknown compound = 15.2 mg = 0.0152 g   (Conversion factor:  1 g = 1000 mg)

Volume of solution = 150.0 mL

Putting values in above equation, we get:

4.54\times 10^{-4}M=\frac{0.0152\times 1000}{\text{Molar mass of unknown compound}\times 150.0}\\\\\text{Molar mass of unknown compound}=\frac{0.0152\times 1000}{150.0\times 4.54\times 10^{-4}}=223.2g/mol

Hence, the molar mass of the unknown compound is 223.2 g/mol

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I don’t know how to do this properly like I got an answer but I don’t know if it’s right
egoroff_w [7]

To calculate this, we will use the chemical equations as math equations and add them.

Firtly, we want the equation for the formation of CH₃CHO(g), so this will be the only product.

The reactants must be only the elements in their standard form, so C(g), O₂(g) and H₂(g). I would be more correct to use C(s), but since we odn't have information for this, we will assume it wants with C(g).

So, the reaction we want is:

C(g)+O_2(g)+H_2(g)\to CH_3CHO(g)

To balance the reaction, we can just do for eqach element separately, maintaining the coefficient of 1 on CH₃CHO(g):

\begin{gathered} 2C(g)+\frac{1}{2}O_2(g)+2H_2(g)\to CH_3CHO\mleft(g\mright) \\ \Delta H=? \end{gathered}

Now, we want to get to this equation adding the equations we want. We will apply the same operations to the enthalpies to get the enthalpy of formation.

The first given equation has the CH₃CHO(g), but it is on the left side and with coefficient of 2, so we need to invert the reaction and divided every coefficient by 2. The same operations have to be applied to the enthalpy, so the sign of the enthalpy will invert and it will be divided by 2:

\begin{gathered} 2CO_2(g)+2H_2O(l)\to CH_3CHO(g)+\frac{5}{2}O_2(g)_{} \\ \Delta H=\frac{2308.4kJ}{2}=1154.2kJ \end{gathered}

The second given equation has both C(g) and O₂(g), but since the third equation also has O₂(g), we will look just for C(g). We need 2 C(g), so we will need to doulbe the equation and its enthalpy:

\begin{gathered} 2C(g)+2O_2(g)\to2CO_2(g) \\ \Delta H=2\cdot-414.0kJ=-828.0kJ \end{gathered}

For the last, we will look into H₂(g) and since all the equations are balanced, O₂(g) will also be balanced by the end of it.

We need 2 H₂(g), so we don't need to do anything with this reaction:

\begin{gathered} 2H_2(g)+O_2(g)\to H_2O(l) \\ \Delta H=-597.4kJ \end{gathered}

Now, we add the equations:

\begin{gathered} \cancel{2CO_2\mleft(g\mright)}+\cancel{2H_2O\mleft(l\mright)}\to CH_3CHO(g)+\cancel{\frac{5}{2}O_2(g)}_{} \\ 2C(g)+\cancel{2O_2(g)}\to\cancel{2CO_2(g)} \\ 2H_2(g)+\cancel{O_2(g)}\to\cancel{H_2O(l)} \\ ------------------------------- \\ 2C(g)+\frac{1}{2}O_2(g)+2H_2(g)\to CH_3CHO(g) \end{gathered}

And we do the same with the enthalpies:

\begin{gathered} \Delta H=1154.2kJ+(-828.0kJ)+(-597.4kJ) \\ \Delta H=1154.2kJ-828.0kJ-597.4kJ \\ \Delta H=-271.2kJ \end{gathered}

This is the enthalpy for this reaction. To get the molar enthalpy of formation, we need to divide this value by the coefficient of CH₃CHO(g). Since this coefficient is 1, we have:

\Delta H_m=-\frac{271.2kJ}{1mol}=-271.2kJ\/mol

So, the molar enthalpy of formation given the data is -271.2 kJ/mol.

4 0
1 year ago
`I am holding a balloon containing 439 mL of gas over my fireplace. The temperature and pressure of the gas inside the balloon i
Andrew [12]

Answer:

- 0.07 °C

Explanation:

At constant pressure and number of moles, Using Charle's law  

\frac {V_1}{T_1}=\frac {V_2}{T_2}

Given ,  

V₁ = 439 mL  = 0.439 L ( 1 L = 0.001 mL )

V₂ = 0.378 L

T₁ = 317.15 K

T₂ = ?

Using above equation as:

\frac{0.439}{317.15}=\frac{0.378}{T_2}

T_2=\frac{0.378\cdot \:317.15}{0.439}=273.08\ K

The conversion of T(K) to T( °C) is shown below:

T( °C) = T(K) - 273.15  

So, <u>T = 273.08 - 273.15 °C = - 0.07 °C</u>

3 0
3 years ago
Arrange these molecules in order of decreasing mass: C​6​H​14​ , NO​2​ , Fe​2​O​3 ​, and CaCO​
babunello [35]

The following is the arrangement of the given molecules in decreasing order of mass: \text{ Fe2O3} > \text{C6H14} > \text{CaCO} > \text{NO2}

<u>Solution:</u>

First inorder to arrange the elements in descending order of their mass we have to calculate the molecular mass of each element. The calculation is as follows:

<u>Mass of C6H14:</u>

C\rightarrow6\times12.01 = 72.06

H\rightarrow14\times1.008 = 14.112

<em>Mass of C6H14 is 86.172</em>

<u>Mass of NO2:</u>

N\rightarrow1\times14.0067 = 14.0067

O\rightarrow2\times15.9994 = 31.9988

<em>Mass of NO2 is 46.0055</em>

<u>Mass of Fe​2​O3:</u>

Fe\rightarrow2\times55.845 = 111.69

O\rightarrow3\times15.9994 = 47.9982

<em>Mass of Fe2O3 is 159.6882</em>

<u>Mass of CaCO:</u>

Ca\rightarrow1\times40.078 = 40.078

C\rightarrow1\times12.01 = 12.01

O\rightarrow1\times15.9994 = 15.9994

<em>Mass of CaCO will be 68.0874</em>

So, the order will be 159.6882>86.172>68.0874>46.0055 which is \text{ Fe2O3} > \text{C6H14} > \text{CaCO} > \text{NO2}

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3 years ago
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tresset_1 [31]

Answer:

B) Synthesis reaction

Explanation:

synthesis reactions because they take apart larger molecules or compounds

Hope that helps

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posledela
I think the answer to this is A
5 0
3 years ago
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