Answer:
(a) r = 6.26 * 10⁻⁷cm
(b) r₂ = 6.05 * 10⁻⁷cm
Explanation:
Using the sedimentation coefficient formula;
s = M(1-Vρ) / Nf ; where s is sedimentation coefficient, M is molecular weight, V is specific volume of protein, p is density of the solvent, N is Avogadro number, f if frictional force = 6πnr, n is viscosity of the medium, r is radius of particle
s = M ( 1 - Vρ) / N*6πnr
making r sbjct of formula, r = M (1 - Vρ) / N*6πnrs
Note: S = 10⁻¹³ sec, 1 KDalton = 1 *10³ g/mol, I cP = 0.01 g/cm/s
r = {(3.1 * 10⁵ g/mol)(1 - (0.732 cm³/g)(1 g/cm³)} / { (6.02 * 10²³)(6π)(0.01 g/cm/s)(11.7 * 10⁻¹³ sec)
r = 6.26 * 10⁻⁷cm
b. Using the formula r₂/r₁ = s₁/s₂
s₂ = 0.035 + 1s₁ = 1.035s₁
making r₂ subject of formula; r₂ = (s₁ * r₁) / s₂ = (s₁ * r₁) / 1.035s₁
r₂ = 6.3 * 10⁻⁷cm / 1.035
r₂ = 6.05 * 10⁻⁷cm
The freezing point depression is calculated through the equation,
ΔT = (kf) x m
where ΔT is the difference in temperature, kf is the freezing point depression constant (1.86°C/m), and m is the molality. Substituting the known values,
5.88 = (1.86)(m)
m is equal to 3.16m
Recall that molality is calculated through the equation,
molality = number of mols / kg of solvent
number of mols = (3.16)(1.25) = 3.95 moles
Then, we multiply the calculated amount in moles with the molar mass of ethylene glycol and the answer would be 244.9 g.
Answer:
0.6749 M is the concentration of B after 50 minutes.
Explanation:
A → B
Half life of the reaction = 
Rate constant of the reaction = k
For first order reaction, half life and half life are related by:
Initial concentration of A = ![[A]_o=0.900 M](https://tex.z-dn.net/?f=%5BA%5D_o%3D0.900%20M)
Final concentration of A after 50 minutes = ![[A]=?](https://tex.z-dn.net/?f=%5BA%5D%3D%3F)
t = 50 minute
![[A]=[A]_o\times e^{-kt}](https://tex.z-dn.net/?f=%5BA%5D%3D%5BA%5D_o%5Ctimes%20e%5E%7B-kt%7D)
![[A]=0.900 M\times e^{-0.02772 min^{-1}\times 50 minutes}](https://tex.z-dn.net/?f=%5BA%5D%3D0.900%20M%5Ctimes%20e%5E%7B-0.02772%20min%5E%7B-1%7D%5Ctimes%2050%20minutes%7D)
[A] = 0.2251 M
The concentration of A after 50 minutes = 0.2251 M
The concentration of B after 50 minutes = 0.900 M - 0.2251 M = 0.6749 M
0.6749 M is the concentration of B after 50 minutes.
207 is the mass number. 82 would be the atomic number
Answer:
Explanation:
k stand for equilibrium constants in terms of reaction
The higher the value of an equilibrium constant the faster the equilibrium reaction comes to completion.
Consider the example below:
⇄
where
For a faster reaction the numerator i.e. the right hand side of the equation have to be higher than the left hand side (the denominator). therefore the higher the numerator, the higher the value of the equilibrium constant and the faster the reaction get to completion thus option c is correct.
