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Taya2010 [7]
3 years ago
6

Elaborate on the role of activation energy in chemical reactions. A) Decreasing the activation energy leads to higher randomness

within the reaction and an increased reaction rate. B) Activation energy is the minimum energy colliding reactants need to combine and for the chemical reaction to occur. C) The activation energy and randomness indicate the reduced likelihood that the barrier is overcome and a decreased rate. D) Higher activation energy indicates a higher randomness and the energy barrier is overcome with an increased reaction rate.
Chemistry
2 answers:
Zina [86]3 years ago
4 0

<em>B</em><em> </em><em>i</em><em>s</em><em> </em><em>r</em><em>i</em><em>g</em><em>h</em><em>t</em><em> </em><em>a</em><em>n</em><em>s</em><em>w</em><em>e</em><em>r</em><em> </em><em>i</em><em>t</em><em>h</em><em>i</em><em>n</em><em>k</em><em> </em><em>b</em><em>r</em><em>o</em><em>/</em><em>s</em><em>i</em><em>s</em>

Maslowich3 years ago
3 0

Answer:

A and B

Explanation:

The activation energy is the minimum energy necessary for the reaction to happen. It is a barrier, the reaction only occurs if the reactants have that energy.

As higher is the activation energy, as difficult is to the reaction happens, and because of that, the reaction rate will be small. The rate indicates the reaction velocity, which is the velocity of the collisions of the molecules, with more collisions, higher randomness is presented, and higher is the velocity.

A) Correct. As less energy is necessary, as higher is the velocity of the reaction, so the randomness and the rate will increase.

B) Correct. Is the definition of activation energy.

C) Incorrect. They indicate the rate of the reaction, and how easy or not it will be to the reaction happen.

D) Incorrect. As higher is the activation energy, as low is the randomness and the rate of the reaction.

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The precaution to be taken while measuring the temperature of a liquid in a beaker is applying proper heat balance and taking all the required precautions.

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2 years ago
Express the van der Waals equation of state as a virial expansion in powers of 1/Vm and obtain expressions for B and C in terms
nirvana33 [79]

Answer:

PV_{m} = RT[1 + (b-\frac{a}{RT})\frac{1}{V_{m} } + \frac{b^{2} }{V^{2} _{m} } + ...]

B = b -a/RT

C = b^2

a = 1.263 atm*L^2/mol^2

b = 0.03464 L/mol

Explanation:

In the given question, we need to express the van der Waals equation of state as a virial expansion in powers of 1/Vm and obtain expressions for B and C in terms of the parameters a and b. Therefore:

Using the van deer Waals equation of state:

P = \frac{RT}{V_{m}-b } - \frac{a}{V_{m} ^{2} }

With further simplification, we have:

P = RT[\frac{1}{V_{m}-b } - \frac{a}{RTV_{m} ^{2} }]

Then, we have:

P = \frac{RT}{V_{m} } [\frac{1}{1-\frac{b}{V_{m} } } - \frac{a}{RTV_{m} }]

Therefore,

PV_{m} = RT[(1-\frac{b}{V_{m} }) ^{-1} - \frac{a}{RTV_{m} }]

Using the expansion:

(1-x)^{-1} = 1 + x + x^{2} + ....

Therefore,

PV_{m} = RT[1+\frac{b}{V_{m} }+\frac{b^{2} }{V_{m} ^{2} } + ... -\frac{a}{RTV_{m} }]

Thus:

PV_{m} = RT[1 + (b-\frac{a}{RT})\frac{1}{V_{m} } + \frac{b^{2} }{V^{2} _{m} } + ...]           equation (1)

Using the virial equation of state:

P = RT[\frac{1}{V_{m} }+ \frac{B}{V_{m} ^{2}}+\frac{C}{V_{m} ^{3} }+ ...]

Thus:

PV_{m} = RT[1+ \frac{B}{V_{m} }+ \frac{C}{V_{m} ^{2} } + ...]     equation (2)

Comparing equations (1) and (2), we have:

B = b -a/RT

C = b^2

Using the measurements on argon gave B = −21.7 cm3 mol−1 and C = 1200 cm6 mol−2 for the virial coefficients at 273 K.

b = \sqrt{C} = \sqrt{1200} = 34.64[tex]cm^{3}/mol[/tex] = 0.03464 L/mol

a = (b-B)*RT = (34.64+21.7)*(1L/1000cm^3)*(0.0821)*(273) = 1.263 atm*L^2/mol^2

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Write a balanced net ionic equation for the reaction of aqueous solutions of baking soda (NaHCO3) and acetic acid.(A) HCO3–(aq)
IgorC [24]

<u>Answer:</u> The correct answer is Option C.

<u>Explanation:</u>

Net ionic equation of any reaction does not include any spectator ions.

Spectator ions are defined as the ions which does not get involved in a chemical equation. They are found on both the sides of the chemical reaction when it is present in ionic form.

The chemical equation for the reaction of sodium bicarbonate and acetic acid is given as:

NaHCO_3(aq.)+CH_3COOH(aq.)\rightarrow CH_3COONa(aq.)+H_2O(l)+CO_2(g)

Ionic form of the above equation follows:

Na^+(aq.)+HCO_3^-(aq.)+CH_3COO^-(aq.)+H^+(aq.)\rightarrow CH_3COO^-(aq.)+Na^+(aq.)+H_2O(l)+CO_2(g)

As, sodium and acetate ions are present on both the sides of the reaction. Thus, it will not be present in the net ionic equation and are spectator ions.

The net ionic equation for the above reaction follows:

HCO_3^-(aq.)+H^+(aq.)\rightarrow CO_2(g)+H_2O(l)

Hence, the correct answer is Option C.

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blsea [12.9K]

Answer:hydrogen Peroxide

Explanation:

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Property of Volume changes.

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