The enthalpy of reaction for the combustion of ethane 2CH₃CH₃ + 7O₂ → 4CO₂ + 6H₂O calculated from the average bond energies of the compounds is -2860 kJ/mol.
The reaction is:
2CH₃CH₃ + 7O₂ → 4CO₂ + 6H₂O (1)
The enthalpy of reaction (1) is given by:
(2)
Where:
r: is for reactants
p: is for products
The bonds of the compounds of reaction (1) are:
- 2CH₃CH₃: 2 moles of 6 C-H bonds + 2 moles of 1 C-C bond
- 7O₂: 7 moles of 1 O=O bond
- 4CO₂: 4 moles of 2 C=O bonds
- 6H₂O: 6 moles of 2 H-O bonds
Hence, the enthalpy of reaction (1) is (eq 2):

Therefore, the enthalpy of reaction for the combustion of ethane is -2860 kJ/mol.
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We have been given the condition that carbon makes up 35%
of the mass of the substance and the rest is made up of oxygen. With this, it
can be concluded that 65% of the substance is made up of oxygen. If we let x be
the mass of oxygen in the substance, the operation that would best represent
the scenario is,
<span> x = (0.65)(5.5 g)</span>
<span> <em> </em><span><em>x =
3.575 g</em></span></span>
44. (a) N2O3 (b) SF4 (c) AlCl3 (d) Li2CO3
46. H Br
δ+ δ−
48. The metallic potassium atoms lose one electron and form +1 cations,
and the nonmetallic fluorine atoms gain one electron and form –1 anions.
K → K+
+ e–
19p/19e–
19p/18e–
F + e–
→ F–
9p/9e–
9p/10e–
The ionic bonds are the attractions between K+
cations and F–
anions.
50. See Figure 3.6.
52. (a) covalent…nonmetal-nonmetal (b) ionic…metal-nonmetal
54. (a) all nonmetallic atoms - molecular (b) metal-nonmetal - ionic
56. (a) 7 (b) 4
58. Each of the following answers is based on the assumption that nonmetallic
atoms tend to form covalent bonds in order to get an octet (8) of
electrons around each atom, like the very stable noble gases (other than
helium). Covalent bonds (represented by lines in Lewis structures) and lone
pairs each contribute two electrons to the octet.
(a) oxygen, O
If oxygen atoms form two covalent bonds, they will have an octet of electrons
around them. Water is an example:
H O H
(b) fluorine, F
If fluorine atoms form one covalent bond, they will have an octet of electrons
around them. Hydrogen fluoride, HF, is an example:
H F
(c) carbon, C
If carbon atoms form four covalent bonds, they will have an octet of electrons
around them. Methane, CH4, is an example:
H H
H
H
C
(d) phosphorus, P
If phosphorus atoms form three covalent bonds, they will have an octet
4 3 and 5 are wrong:)
4 is true and 5 is false
4. insulators are really thick materials that keep electrons within their space.
For example, a charger the rubber is the insulators and the electrons are flowing inside of the charger so you don't get shocked.
5. without the force of attraction, there are no atoms:)
for number 3, its a trick question
Hope this helped!
(learned these this year so I didn't forget them:)