Explanation:
The chemical equation is as follows.

And, the given enthalpy is as follows.
;
= 102.5 kJ
Cl-Cl = 243 kJ/mol, O=O = 498 kJ/mol
Since, the bond enthalpy of Cl-Cl is not given so at first, we will calculate the value of Cl-Cl as follows.
102.5 = ![[(\frac{1}{2})x + 498] - [(2)(243)]](https://tex.z-dn.net/?f=%5B%28%5Cfrac%7B1%7D%7B2%7D%29x%20%2B%20498%5D%20-%20%5B%282%29%28243%29%5D)
102.5 = 
102.5 - 12 = 
x = 181 kJ
Now, total bond enthalpy of per mole of ClO is calculated as follows.

x = ![[(\frac{1}{2})181 + (\frac{1}{2})498] - 243](https://tex.z-dn.net/?f=%5B%28%5Cfrac%7B1%7D%7B2%7D%29181%20%2B%20%28%5Cfrac%7B1%7D%7B2%7D%29498%5D%20-%20243)
= 339.5 - 243
= 96.5 kJ
Thus, we can conclude that the value for the enthalpy of formation per mole of ClO(g) is 96.5 kJ.
Chemical change? Need more context.
Answer : The enthalpy of the reaction = -1839.6 KJ
Solution : Given,
= -520.0 KJ/mole
= -1699.8 KJ/mole
The balanced chemical reaction is,

Formula used :


We know that the standard enthalpy of formation of the element is equal to Zero.
Therefore, the enthalpy of formation of (Mn) and (Al) is equal to zero.
Now, put all the values in above formula, we get
![\Delta (H_{f})_{reaction}=[2moles\times (-1699.8 KJ/mole)}+3moles\times (0\text{ KJ/mole}})]-[(3moles\times(-520.0KJ/mole }+4moles\times(0\text{ KJ/mole})]](https://tex.z-dn.net/?f=%5CDelta%20%28H_%7Bf%7D%29_%7Breaction%7D%3D%5B2moles%5Ctimes%20%28-1699.8%20KJ%2Fmole%29%7D%2B3moles%5Ctimes%20%280%5Ctext%7B%20KJ%2Fmole%7D%7D%29%5D-%5B%283moles%5Ctimes%28-520.0KJ%2Fmole%20%7D%2B4moles%5Ctimes%280%5Ctext%7B%20KJ%2Fmole%7D%29%5D)
= (-3399.6) + (1560)
= -1839.6 KJ
Insulation wraps because independent is the variable you are changing to affect the dependent variable (what you are measuring)