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mamaluj [8]
3 years ago
15

Consider the fructose-1,6-bisphosphatase reaction. Calculate the free energy change if the ratio of the concentrations of the pr

oducts to the concentrations of the reactants is 21.321.3 and the temperature is 37.0°C37.0°C ? ΔG°′ΔG°′ for the reaction is −16.7 kJ/mol−16.7 kJ/mol .
Chemistry
1 answer:
enot [183]3 years ago
7 0

Answer:

ΔG = -8.812 kJ/mol

Explanation:

To obtain the free energy of a reaction you can use the expression:

ΔG = ΔG° + RT ln Q

<em>Where: </em>

<em>ΔG° is Standard Gibbs Free energy: -16.7kJ/mol = -16700J/mol</em>

<em>R is gas constant: 8.314472 J/molK</em>

<em>T is absolute temperature (37°C + 273.15 = 310.15K)</em>

<em>And Q is reaction quotient: 21.3</em>

<em />

Replacing in the formula:

ΔG = ΔG° + RT ln Q

ΔG = -16700J/mol + 8.314472J/molK*310.15K ln 21.3

ΔG = -8812.4J/mol

<h3>ΔG = -8.812 kJ/mol</h3>

<em />

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Using the equations 2 Sr(s) + O₂ (g) → 2 SrO (s) ∆H° = -1184 kJ/mol SrO (s) + CO₂ (g) → SrCO₃ (s) ∆H° = -234 kJ/mol CO₂ (g) → C(
kkurt [141]

<u>Answer:</u> The \Delta H^o_{rxn} for the reaction is 72 kJ.

<u>Explanation:</u>

Hess’s law of constant heat summation states that the amount of heat absorbed or evolved in a given chemical equation remains the same whether the process occurs in one step or several steps.

According to this law, the chemical equation is treated as ordinary algebraic expressions and can be added or subtracted to yield the required equation. This means that the enthalpy change of the overall reaction is equal to the sum of the enthalpy changes of the intermediate reactions.

The given chemical reaction follows:

2SrCO_3(s)\rightarrow 2Sr(s)+2C(s)+3O_2(g)      \Delta H^o_{rxn}=?

The intermediate balanced chemical reaction are:

(1) 2Sr(s)+O_2(g)\rightarrow 2SrO(s)    \Delta H_1=-1184kJ

(2) SrO(s)+CO_2(g)\rightarrow SrCO_3(s)     \Delta H_2=-234kJ      ( × 2)

(3) CO_2(g)\rightarrow C(s)+O_2(g)     \Delta H_3=394kJ    ( × 2)

The expression for enthalpy of the reaction follows:

\Delta H^o_{rxn}=[1\times (\Delta H_1)]+[2\times (-\Delta H_2)]+[2\times (\Delta H_3)]

Putting values in above equation, we get:

\Delta H^o_{rxn}=[(1\times (-1184))+(2\times -(-234))+(2\times (394))]=72kJ

Hence, the \Delta H^o_{rxn} for the reaction is 72 kJ.

4 0
3 years ago
The equilibrium concentrations of the reactants and products are [HA]=0.280 M, [H+]=4.00×10−4 M, and [A−]=4.00×10−4 M. Calculate
Tems11 [23]

Answer:

6.24

Explanation:

The following data were obtained from the question:

Concentration of HA, [HA] = 0.280 M,

Concentration of H+, [H+] = 4×10¯⁴ M

Concentration of A-, [A−] = 4×10¯⁴ M

pKa =.?

Next, we shall write the balanced equation for the reaction. This is given below:

HA <===> H+ + A-

Next, we shall determine the equilibrium constant Ka for the reaction. This can be obtained as follow:

Equilibrium constant for a reaction is simply the ratio of concentration of the product raised to their coefficient to the concentration of the reactant raised to their coefficient.

The equilibrium constant for the above equation is given below:

Ka = [H+] [A−] /[HA]

Concentration of HA, [HA] = 0.280 M,

Concentration of H+, [H+] = 4×10¯⁴ M

Concentration of A-, [A−] = 4×10¯⁴ M

Equilibrium constant (Ka) =

Ka = (4×10¯⁴ × 4×10¯⁴) / 0.280

Ka = 1.6×10¯⁷/ 0.280

Ka = 5.71×10¯⁷

Therefore, the equilibrium constant for the reaction is 5.71×10¯⁷

Finally, we shall determine the pka for the reaction as follow:

Equilibrium constant, Ka = 5.71×10¯⁷

pKa =?

pKa = – Log Ka

pKa = – Log 5.71×10¯⁷

pKa = 6.24

Therefore, the pka for the reaction is 6.24.

6 0
3 years ago
Whats between -999 and 1000
Doss [256]
Hello!

Numbers from -998 and 999 are in between -999 and 1000.

I hope this was helpful! c:
7 0
3 years ago
What is the pH of a 3.40 mM of acetic acid, 500 mL in which 50 mL of 1.00 M NaOAc has been added? Ka HOAc is 1.8 x 10-5? What pe
Deffense [45]

Answer:

a) pH = 4.213

b) % dis = 2 %

Explanation:

Ch3COONa → CH3COO- + Na+

CH3COOH ↔ CH3COO- + H3O+

∴ Ka = 1.8 E-5 = ([ CH3COO- ] * [ H3O+ ]) / [ CH3COOH ]

mass balance:

⇒ <em>C</em> CH3COOH + <em>C</em> CH3COONa = [ CH3COOH ] + [ CH3COO- ]

<em>∴ C </em>CH3COOH = 3.40 mM = 3.4 mmol/mL * ( mol/1000mmol)*(1000mL/L)

∴ <em>C</em> CH3COONa = 1.00 M = 1.00 mol/L = 1.00 mmol/mL

⇒ [ CH3COOH ] = 4.4 - [ CH3COO- ]

charge balance:

⇒ [ H3O+ ] + [ Na+ ] = [ CH3COO- ] + [ OH- ]....is negligible [ OH-], comes from water

⇒ [ CH3COO- ] = [ H3O+ ] + 1.00

⇒ Ka = (( [ H3O+ ] + 1 )* [ H3O+ ]) / ( 3.4 - [ H3O+])) = 1.8 E-5

⇒ [ H3O+ ]² + [ H3O+ ] = 6.12 E-5 - 1.8 E-5 [ H3O+ ]

⇒ [ H3O+ ]² + [ H3O+ ] - 6.12 E-5 = 0

⇒  [ H3O+ ] = 6.12 E-5 M

⇒ pH = - Log [ H3O+ ] = 4.213

b) (% dis)* mol acid = <em>C</em> CH3COOH = 3.4

∴ mol CH3COOH = 500*3.4 = 1700 mmol = 1.7 mol

⇒ % dis = 3.4 / 1.7 = 2 %

7 0
3 years ago
The strongest elemental oxidizing agents are found in the _________ _________ region of the periodic table while the strongest r
Slav-nsk [51]

Strongest reducing agents are in Group 1 . For example lithium. The strongest oxidising agents are in Group 7 , For example Fluorine.

3 0
3 years ago
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