Answer:
1.7 mL
Explanation:
<em>A chemist must prepare 550.0 mL of hydrochloric acid solution with a pH of 1.60 at 25 °C. He will do this in three steps: Fill a 550.0 mL volumetric flask about halfway with distilled water. Measure out a small volume of concentrated (8.0 M) stock hydrochloric acid solution and add it to the flask. Fill the flask to the mark with distilled water. Calculate the volume of concentrated hydrochloric acid that the chemist must measure out in the second step. Round your answer to 2 significant digits.</em>
Step 1: Calculate [H⁺] in the dilute solution
We will use the following expresion.
pH = -log [H⁺]
[H⁺] = antilog - pH = antilog -1.60 = 0.0251 M
Since HCl is a strong monoprotic acid, the concentration of HCl in the dilute solution is 0.0251 M.
Step 2: Calculate the volume of the concentrated HCl solution
We want to prepare 550.0 mL of a 0.0251 M HCl solution. We can calculate the volume of the 8.0 M solution using the dilution rule.
C₁ × V₁ = C₂ × V₂
V₁ = C₂ × V₂/C₁
V₁ = 0.0251 M × 550.0 mL/8.0 M = 1.7 mL
The answer is: " 56 g CaCl₂ " .
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Explanation:
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2.0 M CaCl₂ = 2.0 mol CaCl₂ / L ;
Since: "M" = "Molarity" (measurement of concentration);
= moles of solute per L {"Liter"} of solution.
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Note the exact conversion: 1000 mL = 1 L .
Given: 250 mL ;
250 mL = ? L ? ;
250 mL * (1 L / 1000 L) = (250/1000) L = 0.25 L .
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(2.0 mol CaCl₂ / L ) * (0.25L) = (2.0) * (0.25) mol = 0.50 mol CaCl₂ ;
We have: 0.50 mol CaCl₂ ; Convert to "g" (grams):
→ 0.50 mol CaCl₂ .
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1 mol CaCl₂ = ? g ?
From the Periodic Table of Elements:
1 mol Ca = 40.08 g
1 mol Cl = <span>35.45 g .
</span>
There are 2 atoms of Cl in " CaCl₂ " ;
→ Note the subscript, "2", in the " Cl₂ " ;
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So, to calculate the molar mass of "CaCl₂" :
40.08 g + 2(35.45 g) =
40.08 g + 70.90 g = 110.98 g ; round to 4 significant figures;
→ round to 111 g/mol .
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So:
→ 0.50 mol CaCl₂ = ? g CaCl₂ ? ;
→ 0.50 mol CaCl₂ * (111 g CaCl₂ / mol CaCl₂) ;
= (0.50) * (111 g) CaCl₂ ;
= 55.5 g CaCl₂ ;
→ round to 2 significant figures;
→ 56 g CaCl₂ .
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The answer is: " 56 g CaCl₂ " .
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Answer: Bromide is many orders of magnitude better than fluoride in leaving group ability
Explanation:
As Size of an atom Increases, the Basicity Decreases this is because if we move downwards from the top of the periodic table to the bottom of the periodic table, the size of an atom increases. As size increases, basicity will decrease, meaning the element will be less likely to act as a base implying that the element will be less likely to share its electrons.
in the same vein. With an increase in size, basicity decreases, making the ability of the leaving group to leave increase to increase . This can be seen in the halogens going down the group from
F--- worst
Cl----fair
Br ----good
I-----excellent
with fluorine having the worst ability to leave than Bromine which is better in terms of the leaving group ability.
Answer:
E) 2.38
Explanation:
The pH of any solution , helps to determine the acidic strength of the solution ,
i.e. ,
- Lower the value of pH , higher is its acidic strength
and ,
- Higher the value of pH , lower is its acidic strength .
pH is given as the negative log of the concentration of H⁺ ions ,
hence ,
pH = - log H⁺
From the question ,
the concentration of the solution is 0.0042 M , and being it a strong acid , dissociates completely to its respective ions ,
Therefore , the concentration of H⁺ = 0.0042 M .
Hence , using the above equation , the value of pH can be calculated as follows -
pH = - log H⁺
pH = - log ( 0.0042 M )
pH = 2.38 .
