n a system for separating gases a tank containing a mixture of hydrogen and carbon dioxide is connected to a much larger tank wh
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Answer : The correct answer for change in freezing point = 1.69 ° C
Freezing point depression :
It is defined as depression in freezing point of solvent when volatile or non volatile solute is added .
SO when any solute is added freezing point of solution is less than freezing point of pure solvent . This depression in freezing point is directly proportional to molal concentration of solute .
It can be expressed as :
ΔTf = Freezing point of pure solvent - freezing point of solution = i* kf * m
Where : ΔTf = change in freezing point (°C)
i = Von't Hoff factor
kf =molal freezing point depression constant of solvent.
m = molality of solute (m or )
Given : kf = 1.86
m = 0.907 )
Von't Hoff factor for non volatile solute is always = 1 .Since the sugar is non volatile solute , so i = 1
Plugging value in expression :
ΔTf = 1* 1.86 * 0.907
)
ΔTf = 1.69 ° C
Hence change in freezing point = 1.69 °C
Let us consider each statement one by one
a) Catalysts are the substance which alter the reaction pathway where activation energy of reaction is less that the un catalyzed reaction. They are not used up in the reaction . the catalyst is restored in the reaction.
b) As mentioned above, the catalyst speed up reaction by lowering the activation energy
c) During a reaction the reactants are consumed up and products are formed. so there is a decrease in concentration of reactant.
Thus all the above statements are true.
D) the rate of decrease in concentration of reactants depends upon the coefficient of reactant in balanced chemical reaction.
For example
Here the rate of decrease in concentration of hydrogen will be double the rate of decrease in concentration of oxygen.