The ph of the best buffer is 4.74
The given acetic acid is a weak acid
The equation of the pH of the buffer
pH = pKa + log ( conjugate base / weak acid ).
For best buffer the concentration of the weak acid and its conjugate base is equal.
pH = pKa + log 1
pH = pKa + 0
pH = pKa
given Ka = 1.8 × 10⁻⁵
pKa = - log ka
pH = -log ( 1.8 × 10⁻⁵ )
pH = 4. 74
Hence the pH of the best buffer is 4.74
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Answer: There are
molecules present in 7.62 L of
at
and 722 torr.
Explanation:
Given : Volume = 7.62 L
Temperature = 
Pressure = 722 torr
1 torr = 0.00131579
Converting torr into atm as follows.

Therefore, using the ideal gas equation the number of moles are calculated as follows.
PV = nRT
where,
P = pressure
V = volume
n = number of moles
R = gas constant = 0.0821 L atm/mol K
T = temperature
Substitute the values into above formula as follows.

According to the mole concept, 1 mole of every substance contains
atoms. Hence, number of atoms or molecules present in 0.244 mol are calculated as follows.

Thus, we can conclude that there are
molecules present in 7.62 L of
at
and 722 torr.