The rate equation is given as:
k = A e^(- Ea / RT)
Dividing state 1 and state 2:
k1/k2 = e^(- Ea / RT1) / e^(- Ea / RT2)
k1/k2 = e^[- Ea / RT1 - (- Ea / RT2)]
k1/k2 = e^[- Ea / RT1 + Ea / RT2)]
Taking the ln of both sides:
ln (k1/k2) = - Ea / RT1 + Ea / RT2
ln (k1/k2) = - Ea / R (1/T1 - 1/T2)
Since k2 = 4k1, therefore k1/k2 = ¼
ln (1/4) = [- (56,000 J/mol) / (8.314 J / mol K)] (1/273
K – 1/ T2)
2.058 x 10^-4 = 1/273 – 1/T2
T2 = 289.25 K
Answer:
metal : Mercury(Hg)
non metal : bromine (Br)
Explanation:
mercury is liquid at room temperature and pressure and the same as bromine
Answer:
Because it is closer to earth than the other blue giant stars.
Explanation:
The sun is closer to earth than any other big star which means we see it bigger.
Answer:
The metalloids; boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te), polonium (Po) and astatine (At) are the elements found along the step like line between metals and non-metals of the periodic table.
Elements: Germanium; Boron; Arsenic
Explanation:
Answer:
The correct option is: (D) -2.4 kJ/mol
Explanation:
<u>Chemical reaction involved</u>: 2PG ↔ PEP
Given: The standard Gibb's free energy change: ΔG° = +1.7 kJ/mol
Temperature: T = 37° C = 37 + 273.15 = 310.15 K (∵ 0°C = 273.15K)
Gas constant: R = 8.314 J/(K·mol) = 8.314 × 10⁻³ kJ/(K·mol) (∵ 1 kJ = 1000 J)
Reactant concentration: 2PG = 0.5 mM
Product concentration: PEP = 0.1 mM
Reaction quotient: ![Q_{r} =\frac{\left [ PEP \right ]}{\left [ 2PG \right ]} = \frac{0.1 mM}{0.5 mM} = 0.2](https://tex.z-dn.net/?f=Q_%7Br%7D%20%3D%5Cfrac%7B%5Cleft%20%5B%20PEP%20%5Cright%20%5D%7D%7B%5Cleft%20%5B%202PG%20%5Cright%20%5D%7D%20%3D%20%5Cfrac%7B0.1%20mM%7D%7B0.5%20mM%7D%20%3D%200.2)
<u>To find out the Gibb's free energy change at 37° C (310.15 K), we use the equation:</u>
![\Delta G = 1.7 kJ/mol + [2.303 \times (8.314 \times 10^{-3} kJ/(K.mol))\times (310.15 K)] log (0.2)](https://tex.z-dn.net/?f=%5CDelta%20G%20%3D%201.7%20kJ%2Fmol%20%2B%20%5B2.303%20%5Ctimes%20%288.314%20%5Ctimes%2010%5E%7B-3%7D%20kJ%2F%28K.mol%29%29%5Ctimes%20%28310.15%20K%29%5D%20log%20%280.2%29)
![\Delta G = 1.7 + [5.938] \times (-0.699) = 1.7 - 4.15 = (-2.45 kJ/mol)](https://tex.z-dn.net/?f=%5CDelta%20G%20%3D%201.7%20%2B%20%5B5.938%5D%20%5Ctimes%20%28-0.699%29%20%3D%201.7%20-%204.15%20%3D%20%28-2.45%20kJ%2Fmol%29)
<u>Therefore, the Gibb's free energy change at 37° C (310.15 K): </u><u>ΔG = (-2.45 kJ/mol)</u>
