Explanation:
P(aq)+Q(aq)⇌3R(aq)
This problem involves applying LeChatelier's principle.
LeChatelier's principle states that whenever a system in equilibrium is disturbed, the equilibrium position would change in order to annul that change.
1) Increase [P]
This would cause the equilibrium position to shift to the right. This is because more reactions have been added, to annul that change more products have to be formed.
2) Increase [Q]
This would cause the equilibrium position to shift to the right. This is because more reactions have been added, to annul that change more products have to be formed.
3) Increase [R]
This would cause the equlibrium position to shift to the left. This is because more products have been formed, to annul that change more reactants have to be formed.
4) Decrease [P]
This would cause the equlibrium position to shift to the left. This is because there are now less reactants, to annul that change more reactants have to be formed.
5) Decrease [Q]
This would cause the equilibrium position to shift to the left. This is because there are now less reactants, to annul that change more reactants have to be formed.
6) Decrease [R]
This would cause the equilibrium position to shift to the right. This is because there are now less products, to annul that change more products have to be formed.
7) Triple [P] and reduce [Q] to one third
No shift in the direction of the net reaction because both changes cancels each other.
8) Triple both [Q] and [R]
No shift in the direction of the net reaction because both changes cancels each other.
= 0.045 mol NH₃