Answer:
The volume of the gas will be 573.52 mL.
Explanation:
Boyle’s law states that <u>the pressure of a fixed amount of gas at a constant temperature is inversely proportional to the volume of the gas</u>.
The equation for Boyle's law is:
P₁V₁ = P₂V₂
We want to know V₂, that is, the volume of the container after the compression. We rearrange the equation and calculate:
V₂ = P₁V₁ ÷ P₂
V₂ = 1.14 atm × 815 mL ÷ 1.62 atm = 573.52 mL
The difference between the calculated voltage (based on standard potentials) and the actual voltage required to cause electrolysis is called overvoltage.
<h3>Electrolysis </h3>
Electrolysis is the technique of causing a chemical change in a substance by passing an electric current through it. The substance either loses or gets an electron during the chemical transition (oxidation or reduction). The procedure is carried out in an electrolytic cell, a device made up of positive and negative electrodes that are kept apart and submerged in a solution with ions that are both positively and negatively charged. The chemical that needs to be converted might either be dissolved in the solution or could form the electrode. The negatively charged electrode (cathode) receives electrical current (i.e., electrons), which travels there and combines with the components of the solution to convert them (reduced).
Learn more about electrolysis here:
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Answer:
(a) Cu²⁺ +2e⁻ ⇌ Cu
(c) 0.07 V
Explanation:
(a) Cu half-reaction
Cu²⁺ + 2e⁻ ⇌ Cu
(c) Cell voltage
The standard reduction potentials for the half-reactions are+
<u> E°/V
</u>
Cu²⁺ + 2e⁻ ⇌ Cu; 0.34
Hg₂Cl₂ + 2e⁻ ⇌ 2Hg + 2Cl⁻; 0.241
The equation for the cell reaction is
E°/V
Cu²⁺(0.1 mol·L⁻¹) + 2e⁻ ⇌ Cu; 0.34
<u>2Hg + 2Cl⁻ ⇌ Hg₂Cl₂ + 2e⁻; </u> <u>-0.241
</u>
Cu²⁺(0.1 mol·L⁻¹) + 2Hg + 2Cl⁻ ⇌ Cu + Hg₂Cl₂; 0.10
The concentration is not 1 mol·L⁻¹, so we must use the Nernst equation
(ii) Calculations:
T = 25 + 273.15 = 298.15 K
![Q = \dfrac{\text{[Cl}^{-}]^{2}}{ \text{[Cu}^{2+}]} = \dfrac{1}{0.1} = 10\\\\E = 0.10 - \left (\dfrac{8.314 \times 298.15 }{2 \times 96485}\right ) \ln(10)\\\\=0.010 -0.01285 \times 2.3 = 0.10 - 0.03 = \textbf{0.07 V}\\\text{The cell potential is }\large\boxed{\textbf{0.07 V}}](https://tex.z-dn.net/?f=Q%20%3D%20%5Cdfrac%7B%5Ctext%7B%5BCl%7D%5E%7B-%7D%5D%5E%7B2%7D%7D%7B%20%5Ctext%7B%5BCu%7D%5E%7B2%2B%7D%5D%7D%20%3D%20%5Cdfrac%7B1%7D%7B0.1%7D%20%3D%2010%5C%5C%5C%5CE%20%3D%200.10%20-%20%5Cleft%20%28%5Cdfrac%7B8.314%20%5Ctimes%20298.15%20%7D%7B2%20%5Ctimes%2096485%7D%5Cright%20%29%20%5Cln%2810%29%5C%5C%5C%5C%3D0.010%20-0.01285%20%5Ctimes%202.3%20%3D%200.10%20-%200.03%20%3D%20%5Ctextbf%7B0.07%20V%7D%5C%5C%5Ctext%7BThe%20cell%20potential%20is%20%7D%5Clarge%5Cboxed%7B%5Ctextbf%7B0.07%20V%7D%7D)