The reaction between ethylene and hydrogen bromide to form ethyl bromide is carried out in a continuous reactor. The product str
eam is analyzed and found to contain 58.7 mol% C2H5Br and 18.3 mol% HBr. The feed to the reactor conains only ethylene and hydrogen bromide. Calculate the fractional conversion of the limiting reactant and the percentage by which the other reactant is in excess. If the molar flow rate of the feed stream is 305 mol/s, what is the extent of reaction
The first thing to do is to write out the chemical equation showing the reaction between the two chemical compounds.
C2H4 + HBr ------------------------> C2H5Br.
The chemical species/compounds reacted in the ratio of 1 : 1 : 1. That is one mole of C2H4 reacted with one mole of HBr to give one mole of C2H5Br.
So, we are given; C2H5Br = 58.7 mol%, HBr = 18.3 mol%. Thus, for C2H4, we have [ 100 - (58.7 + 18.3)] = 23 mol%. Therefore, the limiting reagent is HBr.
Therefore, the total value of the flow rate in the feed = (HBr in feed) mol/s + (C2H4 in feed) mol/s = (58.7 + 18.3)mol/s + (58.7 + 23) mol/s =( 77 + 81.7) mol/s = 158.7 mol/s. .
Considering that CCL3F gas behave like an ideal gas then we can use the Ideal Gas Law <span>PV = nRT, however is an approximation and not the only way to resolve this problem with the given data..So,at the end of the solution I am posting some sources for further understanding and a expanded point of view. </span>
<span>Data: P= 856torr, T = 300K, V= 1.1L, R = 62.36 L Torr / KMol </span>
<span>Solving and substituting in the Gas equation for n = PV / RT = (856)(1.1L) /( 62.36)(300) = 0.05 Mol. This RESULT is of any gas. To tie it up to our gas we need to look for its molecular weight:MW of CCL3F = 137.7 gm/mol. </span>
<span>Then : 0.05x 137.5 = 6.88gm of vapor </span>
<span>If we sustract the vapor weight from the TOTAL weight of liquid we have: 11.5gm - 6.88gm = 4.62 gm of liquid.d</span>
An elementary reaction is a chemical reaction in which one or more chemical species react directly to form products in a single reaction step and with a single transition state.
Taking into account the definition of calorimetry, 0.0185 moles of water are required.
<h3>Calorimetry</h3>
Calorimetry is the measurement and calculation of the amounts of heat exchanged by a body or a system.
Sensible heat is defined as the amount of heat that a body absorbs or releases without any changes in its physical state (phase change).
So, the equation that allows to calculate heat exchanges is:
Q = c× m× ΔT
where Q is the heat exchanged by a body of mass m, made up of a specific heat substance c and where ΔT is the temperature variation.
<h3>Mass of water required</h3>
In this case, you know:
Heat= 92.048 kJ
Mass of water = ?
Initial temperature of water= 34 ºC
Final temperature of water= 100 ºC
Specific heat of water = 4.186
Replacing in the expression to calculate heat exchanges:
92.048 kJ = 4.186 × m× (100 °C -34 °C)
92.048 kJ = 4.186 × m× 66 °C
m= 92.048 kJ ÷ (4.186 × 66 °C)
<u><em>m= 0.333 grams</em></u>
<h3>Moles of water required</h3>
Being the molar mass of water 18 , that is, the amount of mass that a substance contains in one mole, the moles of water required can be calculated as: