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Gemiola [76]
3 years ago
6

A balloon contains 0.5 L of air at 101.5 kPa. You squeeze it to a volume of 0.25 L. What is the pressure of air inside the ballo

on? Assume the temperature and amount of gas remain constant.
a.50.8 kPa
b.0.25 kPa
c.102 kPa
d.203 kPa
Chemistry
1 answer:
Igoryamba3 years ago
4 0
The answer would be D. 203kPa




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During an experiment, 95 grams of calcium carbonate reacted with an excess amount of hydrochloric acid. If the percent yield of
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Answer:

Actual yield: 86.5 grams.

Explanation:

How many moles of formula units in 95 grams of calcium carbonate \rm CaCO_3?

Refer to a modern periodic table for relative atomic mass data:

  • Ca: 40.078;
  • C: 12.011;
  • O: 15.999.

Formula mass of \rm CaCO_3:

M(\mathrm{CaCO_3})  = \underbrace{1\times 40.078}_{\rm Ca} + \underbrace{1\times 12.011}_{\rm C} + \underbrace{3\times 15.999}_{\rm O} = \rm 100.086\;g\cdot mol^{-1}.

\displaystyle n(\mathrm{CaCO_3}) = \frac{m(\mathrm{CaCO_3})}{M(\mathrm{CaCO_3})} = \rm \frac{95\;g}{100.086\;g\cdot mol^{-1}} = 0.949184\;mol.

How many moles of \rm CaCl_2 will be produced?

The coefficient in front of \rm CaCO_3 in the chemical equation is the same as that in front of \rm CaCl_2. That is:

\displaystyle \frac{n(\rm CaCl_2)}{n(\rm CaCO_3)} = 1.

\displaystyle n(\mathrm{CaCl_2}) = n(\mathrm{CaCO_3})\cdot \frac{n(\rm CaCl_2)}{n(\rm CaCO_3)} = n(\mathrm{CaCO_3}) = \rm 0.949184\;mol.

What's the theoretical yield of calcium chloride? In other words, what's the mass of \rm 0.949184\;mol of \rm CaCl_2?

Again, refer to a periodic table for relative atomic data:

  • Ca: 40.078;
  • Cl: 35.45.

M(\mathrm{CaCl_2}) = \underbrace{1\times 40.078}_{\rm Ca} + \underbrace{2\times 35.45}_{\rm Cl} = \rm 110.978\;g\cdot mol^{-1}.

\begin{aligned}m(\mathrm{CaCl_2}) &= n(\mathrm{CaCl_2})\cdot M(\mathrm{CaCl_2})\\ &= \rm 0.949184\;mol\times 110.978\;g\cdot mol^{-1}\\ &= \rm 105.339\; g\end{aligned}.

What's the actual yield of calcium chloride?

\displaystyle \text{Percentage Yield} = \frac{\text{Actual Yield}}{\text{Theoretical Yield}}\times 100\%.

\displaystyle \begin{aligned}\text{Actual Yield} &= \text{Theoretical Yield}\cdot \frac{\text{Percentage Yield}}{100\%}\\ &=\rm 105.339\; g \times \frac{82.15\%}{100\%}\\&= \rm 86.5\;g \end{aligned}.

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When the equation Sn + HNO₃ → SnO₂ + NO₂ + H₂O is balanced in acidic solution, what is the smallest whole-number coefficient for
balu736 [363]

Answer:

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Explanation:

Hello,

In this case, for the given reaction we first assign the oxidation state for each species:

Sn^0 + H^+N^{5+}O^{-2}_3 \rightarrow Sn^{4+}O_2 + N^{4+}O^{2-}_2 + H^+_2O^-

Whereas the half reactions are:

Sn^0+2H_2O \rightarrow Sn^{4+}O_2 +4H^++4e^-\\\\H^++H^+N^{5+}O^{-2}_3 +1e^-\rightarrow  N^{4+}O^{2-}_2+H_2O

Next, we exchange the transferred electrons:

1\times(Sn^0+2H_2O \rightarrow Sn^{4+}O_2 +4H^++4e^-)\\\\4\times (H^++H^+N^{5+}O^{-2}_3 +1e^-\rightarrow  N^{4+}O^{2-}_2+H_2O)\\\\\\Sn^0+2H_2O \rightarrow Sn^{4+}O_2 +4H^++4e^-\\\\4H^++4H^+N^{5+}O^{-2}_3 +4e^-\rightarrow  4N^{4+}O^{2-}_2+4H_2O

Afterwards, we add them to obtain:

Sn^0+2H_2O+4H^++4H^+N^{5+}O^{-2}_3  \rightarrow Sn^{4+}O_2 +4H^++4N^{4+}O^{2-}_2+4H_2O

By adding and subtracting common terms we obtain:

Sn^0+4H^+N^{5+}O^{-2}_3  \rightarrow Sn^{4+}O_2 +4N^{4+}O^{2-}_2+2H_2O

Finally, by removing the oxidation states we have:

Sn + 4HNO_3 \rightarrow SnO_2 + 4NO_2 + 2H_2O

Therefore, the smallest whole-number coefficient for Sn is 1.

Regards.

6 0
3 years ago
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