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Trava [24]
3 years ago
12

A large balloon is initially filled to a volume of 25.0 L at 353 K and a pressure of 2575 mm Hg. What volume of gas will the bal

loon contain at 1.35 atm and 253 K?
Chemistry
1 answer:
bija089 [108]3 years ago
4 0

Answer:

45.0 L is the volume of gas will the balloon contain at 1.35 atm and 253 K.

Explanation:

Using Ideal gas equation for same mole of gas as

\frac {{P_1}\times {V_1}}{T_1}=\frac {{P_2}\times {V_2}}{T_2}

Given ,  

V₁ = 25.0 L

V₂ = ?

P₁ = 2575 mm Hg

Also, P (atm) = P (mm Hg) / 760

P₁ = 2575 / 760 atm = 3.39 atm

P₂ = 1.35 atm

T₁ = 353 K

T₂ = 253 K

Using above equation as:

\frac {{P_1}\times {V_1}}{T_1}=\frac {{P_2}\times {V_2}}{T_2}

\frac{{3.39}\times {25.0}}{353}=\frac{{1.35}\times {V_2}}{253}

\frac{1.35V_2}{253}=\frac{3.39\times \:25}{353}

Solving for V₂ , we get:

<u>V₂ = 45.0 L</u>

45.0 L is the volume of gas will the balloon contain at 1.35 atm and 253 K.

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An equilibrium mixture of PCl5(g), PCl3(g), and Cl2(g) has partial pressures of 217.0 Torr, 13.2 Torr, and 13.2 Torr, respective
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Answer:

The new partial pressures after equilibrium is reestablished:

PCl_3,p_1'=6.798 Torr

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Explanation:

PCl_3(g) + Cl_2(g)\rightleftharpoons PCl_5(g)

At equilibrium before adding chlorine gas:

Partial pressure of the PCl_3=p_1=13.2 Torr

Partial pressure of the Cl_2=p_2=13.2 Torr

Partial pressure of the PCl_5=p_3=217.0 Torr

The expression of an equilibrium constant is given by :

K_p=\frac{p_1}{p_1\times p_2}

=\frac{217.0 Torr}{13.2 Torr\times 13.2 Torr}=1.245

At equilibrium after adding chlorine gas:

Partial pressure of the PCl_3=p_1'=13.2 Torr

Partial pressure of the Cl_2=p_2'=?

Partial pressure of the PCl_5=p_3'=217.0 Torr

Total pressure of the system = P = 263.0 Torr

P=p_1'+p_2'+p_3'

263.0Torr=13.2 Torr+p_2'+217.0 Torr

p_2'=32.8 Torr

PCl_3(g) + Cl_2(g)\rightleftharpoons PCl_5(g)

At initail

(13.2) Torr     (32.8) Torr                        (13.2) Torr

At equilbriumm

(13.2-x) Torr     (32.8-x) Torr                        (217.0+x) Torr

K_p=\frac{p_3'}{p_1'\times p_2'}

1.245=\frac{(217.0+x)}{(13.2-x)(32.8-x)}

Solving for x;

x = 6.402 Torr

The new partial pressures after equilibrium is reestablished:

p_1'=(13.2-x) Torr=(13.2-6.402) Torr=6.798 Torr

p_2'=(32.8-x) Torr=(32.8-6.402) Torr=26.398 Torr

p_3'=(217.0+x) Torr=(217+6.402) Torr=223.402 Torr

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