<h2>Answer : Law of conservation of mass</h2><h3>Explanation :</h3>
The law of conservation of mass states that in any reaction mass is neither created nor lost it has to remain constant in a system.
In this case, when the reaction setup was done in normal way the mass was lost in surrounding was not considered nor being calculated; whereas when the reaction was studied in a closed system where the gas was collected after the reaction the mass changes was noted down which helped to prove the point of law of conservation of mass and energy.
One can consider an example of soda can where the carbonated drink contains pressurized carbon dioxide gas. when opened the gas bubbles gets lost into the surroundings and we don't measure the mass changes. Instead if the soda can was opened in such a way where the gas evolved was measured then the mass changed would remain the same.
Answer:
669.48 kJ
Explanation:
According to the question, we are required to determine the heat change involved.
We know that, heat change is given by the formula;
Heat change = Mass × change in temperature × Specific heat
In this case;
Change in temperature = Final temp - initial temp
= 99.7°C - 20°C
= 79.7° C
Mass of water is 2000 g ( 2000 mL × 1 g/mL)
Specific heat of water is 4.2 J/g°C
Therefore;
Heat change = 2000 g × 79.7 °C × 4.2 J/g°C
= 669,480 joules
But, 1 kJ = 1000 J
Therefore, heat change is 669.48 kJ
A) cesium chloride
B) barium oxide
C) potassium sulfide
D) beryllium chloride
E) hydrogen bromide
F) aluminum fluoride
Answer : The enthalpy of the reaction is, -2552 kJ/mole
Explanation :
According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.
According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.
The given enthalpy of reaction is,
The intermediate balanced chemical reactions are:
(1) 
(2) 
(3) 
(4) 
Now we have to revere the reactions 1 and multiple by 2, revere the reactions 3, 4 and multiple by 2 and multiply the reaction 2 by 2 and then adding all the equations, we get :
(when we are reversing the reaction then the sign of the enthalpy change will be change.)
The expression for enthalpy of the reaction will be,
Therefore, the enthalpy of the reaction is, -2552 kJ/mole
