If I titrate an acid with 255mL of 3.4 M NaOH (base) and reach the equivalence point, how many moles of H+ ions were in the acid
1 answer:
Answer:
Molar Concentration =
=
= 13.33
No. of H+ ions present = 13.33
pH value = - log[13.33]
= -1.12
Explanation:
The equivalence point, or stoichiometric point, of a substance response is the point at which synthetically identical amounts of reactants have been blended. As such, the moles of corrosive are equal to the moles of base, as per the condition (this doesn't really infer a 1:1 molar proportion of acid:base, simply that the proportion is equivalent to in the condition). It tends to be found by methods for a marker, for instance phenolphthalein or methyl orange. The endpoint (identified with, however not equivalent to the equivalence point) alludes to the point at which the marker changes shading in a colorimetric titration.
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Answer:
See explanation and picture below
Explanation:
First, in the case of methyloxirane (Also known as propilene oxide) the mechanism that is taking place there is something similar to a Sn2 mechanism. Although a Sn2 mechanism is a bimolecular substitution taking place in only step, the mechanism followed here is pretty similar after the first step.
In both cases, the H atom of the HBr goes to the oxygen in the molecule. You'll have a OH⁺ in both. However, in the case of methyloxirane the next step is a Sn2 mechanism step, the bromide ion will go to the less substitued carbon, because the methyl group is exerting a steric hindrance. Not a big one but it has a little effect there, that's why the bromide will rather go to the carbon with more hydrogens. and the final product is formed.
In the case of phenyloxirane, once the OH⁺ is formed, the next step is a Sn1 mechanism. In this case, the bond C - OH⁺ is opened on the side of the phenyl to stabilize the OH. This is because that carbon is more stable than the carbon with no phenyl. (A 3° carbon is more stable than a 2° carbon). Therefore, when this bond opens, the bromide will go there in the next step, and the final product is formed. See picture below for mechanism and products.
