Answer:
Kp = 1.41 x 10⁻⁶
Explanation:
We have the chemical equation:
2 A(g) + 3 B(g)⇌ C(g)
In which A and B are the reactants and C is the product. We calculate first the change in the number of moles of gas (Δn or dn):
dn= (sum moles products - sum moles reactants)
= (moles C - (moles A + moles B))
= (1 - (2+3))
= 1 - 5
= -4
We have also the following data:
Kc = 63.2
T= 81∘C + 273 = 354 K
R = 0.082 L.atm/K.mol (it is a constant)
Thus, we introduce the data in the mathematical expression for the relation between Kp and Kc:
= (0.082 L.atm/K.mol x 354 K)⁻⁴ = 1.41 x 10⁻⁶
Answer:
[EtOH] = 2.2M and Wt% EtOH = 10.1% (w/w)
Explanation:
1. Molarity = moles solute / Volume solution in Liters
=> moles solute = mass solute / formula weight of solute = 9.8g/46g·mol⁻¹ = 0.213mol EtOH
=> volume of solution (assuming density of final solution is 1.0g/ml) ...
volume solution = 9.81gEtOH + 87.5gH₂O = 97.31g solution x 1g/ml = 97.31ml = 0.09731 Liter solution
Concentration (Molarity) = moles/Liters = 0.213mol/0.09731L = 2.2M in EtOH
2. Weight Percent EtOH in solution (assuming density of final solution is 1.0g/ml)
From part 1 => [EtOH] = 2.2M in EtOH = 2.2moles EtOH/1.0L soln
= {(2.2mol)(46g/mol)]/1000g soln] x 100% = 10.1% (w/w) in EtOH.
Answer:
Explanation:
Firstly, write the expression for the equilibrium constant of this reaction:
![K_{eq} = \frac{[ADP][Pi]}{ATP}](https://tex.z-dn.net/?f=K_%7Beq%7D%20%3D%20%5Cfrac%7B%5BADP%5D%5BPi%5D%7D%7BATP%7D)
Secondly, we may relate the change in Gibbs free energy to the equilibrium constant using the equation below:
From here, rearrange the equation to solve for K:
Now we know from the initial equation that:
Let's express the ratio of ADP to ATP:
![\frac{[ADP]}{[ATP]} = \frac{[Pi]}{K_{eq}}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BADP%5D%7D%7B%5BATP%5D%7D%20%3D%20%5Cfrac%7B%5BPi%5D%7D%7BK_%7Beq%7D%7D)
Substitute the expression for K:
![\frac{[ADP]}{[ATP]} = \frac{[Pi]}{K_{eq}} = \frac{[Pi]}{e^{-\frac{\Delta G^o}{RT}}}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BADP%5D%7D%7B%5BATP%5D%7D%20%3D%20%5Cfrac%7B%5BPi%5D%7D%7BK_%7Beq%7D%7D%20%3D%20%5Cfrac%7B%5BPi%5D%7D%7Be%5E%7B-%5Cfrac%7B%5CDelta%20G%5Eo%7D%7BRT%7D%7D%7D)
Now we may use the values given to solve:
![\frac{[ADP]}{[ATP]} = \frac{[Pi]}{K_{eq}} = \frac{[Pi]}{e^{-\frac{\Delta G^o}{RT}}} = [Pi]e^{\frac{\Delta G^o}{RT}} = 1.0 M\cdot e^{\frac{-30 kJ/mol}{2.5 kJ/mol}} = 6.14\cdot 10^{-6}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BADP%5D%7D%7B%5BATP%5D%7D%20%3D%20%5Cfrac%7B%5BPi%5D%7D%7BK_%7Beq%7D%7D%20%3D%20%5Cfrac%7B%5BPi%5D%7D%7Be%5E%7B-%5Cfrac%7B%5CDelta%20G%5Eo%7D%7BRT%7D%7D%7D%20%3D%20%5BPi%5De%5E%7B%5Cfrac%7B%5CDelta%20G%5Eo%7D%7BRT%7D%7D%20%3D%201.0%20M%5Ccdot%20e%5E%7B%5Cfrac%7B-30%20kJ%2Fmol%7D%7B2.5%20kJ%2Fmol%7D%7D%20%3D%206.14%5Ccdot%2010%5E%7B-6%7D)
4km I believe is the answer
Due to prescence of any impurity, there will be change in physical properties of any liquid.
