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Scrat [10]
3 years ago
15

What is the energy required to change a spherical drop of water to five smaller spherical drops of equal size? At room temperatu

re, the surface tension of water is 72.0 mJ·m–2. What is the energy required to change a spherical drop of water with a diameter of 1.40 mm to five smaller spherical drops of equal size? The surface area of a sphere of radius r is 4π r2 and the volume is 4π r3/3.
Please explain how you got the...
Chemistry
1 answer:
pav-90 [236]3 years ago
3 0
T<span>his is a straightforward question related to the surface energy of the droplet. </span>

<span>You know the surface area of a sphere is 4π r² and its volume is (4/3) π r³. </span>

<span>With a diameter of 1.4 mm you have an original droplet with a radius of 0.7 mm so the surface area is roughly 6.16 mm² (0.00000616 m²) and the volume is roughly 1.438 mm³. </span>

<span>The total surface energy of the original droplet is 0.00000616 * 72 ~ 0.00044 mJ </span>

<span>The five smaller droplets need to have the same volume as the original. Therefore </span>

<span>5 V = 1.438 mm³ so the volume of one of the smaller spheres is 1.438/5 = 0.287 mm³. </span>

<span>Since this smaller volume still has the volume (4/3) π r³ then r = cube_root(0.287/(4/3) π) = cube_root(4.39) = 0.4 mm. </span>

<span>Each of the smaller droplets has a surface area of 4π r² = 2 mm² or 0.0000002 m². </span>

<span>The surface energy of the 5 smaller droplets is then 5 * 0.000002 * 72.0 = 0.00072 mJ </span>
<span>From this radius the surface energy of all smaller droplets is 0.00072 and the difference in energy is 0.00072- 0.00044 mJ = 0.00028 mJ. </span>

<span>Therefore you need roughly 0.00028 mJ or 0.28 µJ of energy to change a spherical droplet of water of diameter 1.4 mm into 5 identical smaller droplets. </span>
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The detaied steps is as shown in the attached file.

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\bold{\huge{\orange{\underline{ Solution}}}}

\bold{\underline{ Given :- }}

  • <u>We </u><u>have </u><u>250g </u><u>of </u><u>liquid </u><u>water </u><u>and </u><u>it </u><u>needs </u><u>to </u><u>be </u><u>cool </u><u>at </u><u>temperature </u><u>from </u><u>1</u><u>0</u><u>0</u><u>°</u><u> </u><u>C </u><u>to </u><u>0</u><u>°</u><u> </u><u>C</u>
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\bold{\underline{ To \: Find :- }}

  • <u>We </u><u>have </u><u>to </u><u>find </u><u>the</u><u> </u><u>total</u><u> </u><u>number </u><u>of </u><u>joules </u><u>released</u><u>. </u>

\bold{\underline{ Let's \:Begin:- }}

<u>We </u><u>know </u><u>that</u><u>, </u>

Amount of heat energy = mass * specific heat * change in temperature

<u>That </u><u>is, </u>

\sf{\red{ Q = mcΔT }}

<u>Subsitute </u><u>the </u><u>required </u><u>values </u><u>in </u><u>the </u><u>above </u><u>formula </u><u>:</u><u>-</u>

\sf{ Q = 250 × 4.180 ×(0 - 100 )}

\sf{ Q = 250 × 4.180 × - 100 }

\sf{ Q = 250 × - 418}

\sf{\pink{ Q = - 104,500 J }}

Hence, 104,500 J of heat is released to cool 250 grams of liquid water from 100° C to 0° C.

\bold{\underline{ Now :- }}

<u>We </u><u>have </u><u>to </u><u>tell </u><u>whether </u><u>the </u><u>above </u><u>process </u><u>is </u><u>endothermic </u><u>or </u><u>exothermic </u><u>:</u><u>-</u>

Here, In the above process ΔT is negative and as a result of it Q is also negative that means above process is Exothermic

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