Answer:
H2 > N2 > Ar > CO2
Explanation:
Graham's law explains why some gases efuse faster than others. This is due to the difference i their molar mass. Generally; The rate of effusion of gaseous substances is inversely proportional to the square rot of its molar mass.
This means gases with low molar masses would have higher efusion rate compared to gases with higher molar masses.
So now we just need to compare the molar masses of the various gases;
Ar - 39.95
CO2 - 44.01
H2 - 2
N2 - 28.01
To obtain the order in increasing rate, we have to order the gases in decreasing molar mass. This order of increasing rate is given as;
H2 > N2 > Ar > CO2
Answer:
Mostly Para
Explanation:
First, let's assume that the molecule is the toluene (A benzene with a methyl group as radical).
Now the nitration reaction is a reaction in which the nitric acid in presence of sulfuric acid, react with the benzene molecule, to introduce the nitro group into the molecule. The nitro group is a relative strong deactiviting group and is metha director, so, further reactions that occur will be in the metha position.
Now, in this case, the methyl group is a weak activating group in the molecule of benzene, and is always ortho and para director for the simple fact that this molecule (The methyl group) is a donor of electrons instead of atracting group of electrons. Therefore for these two reasons, when the nitration occurs,it will go to the ortho or para position.
Now which position will prefer to go? it's true it can go either ortho or para, however, let's use the steric hindrance principle. Although the methyl group it's not a very voluminous and big molecule, it still exerts a little steric hindrance, and the nitro group would rather go to a position where no molecule is present so it can attach easily. It's like you have two doors that lead to the same place, but in one door you have a kid in the middle and the other door is free to go, you'll rather pass by the door which is free instead of the door with the kid in the middle even though you can pass for that door too. Same thing happens here. Therefore the correct option will be mostly para.
There should be mass balance and the charge balance between the reactants and the products
Mass balance : total no of individual atoms of each type should be balanced before and after the reaction
Charge balance : Overall charge of the reactants should be balanced with the overall charge of the products
You can balance,
1)by just looking at it
2)by Algebraic method given above or
3)by the redox method
You need to know how to get the oxidation numbers in order to use the oxidation method
