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lozanna [386]
2 years ago
7

What would be the original temperature of a gas that has a volume of 2.0 L and a pressure of 2.0 ATM and an unknown temperature

that the volume increased to 3.5 L in its pressure decreased to 1.0 ATM if the final temperature is measured to be 11°C
Chemistry
1 answer:
eduard2 years ago
8 0

Answer:

= 51.57 °C

Explanation:

The combined gas equation shows that P₁V₁/T₁=P₂V₂/T₂ where P represents pressure, V represents volume and T absolute temperature

From the information provided in the question,

Since we are finding the initial or original temperature, we can make T₁ the subject of the formula.

T₁=P₁V₁T₂/P₂V₂

P₁=2.0 ATM

P₂= 1.0 ATM

V₁=2.0 L

V₂= 3.5 L

T₁=?

T₂= (11+273) K=284 K

Using these values in the formula:

T₁= (2.0 ATM × 2.0 L× 284 K)/(1.0 ATM × 3.5 L)

=324.57 K

324.57-273= 51.57 °C

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You place 36.5 ml of 0.266 M Ba(OH)2 in a coffee-cup calorimeter at 25.00°C and add 56.6 ml of 0.648 M HCl, also at 25.00°C. Aft
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Answer : The enthalpy of reaction (\Delta H_{rxn}) is, -96.9 kJ/mole

Explanation :

First we have to calculate the mass of solution.

Mass=Density\times Volume

Volume of solution = Volume of HCl + Volume of Ba(OH)_2

Volume of solution = 56.6 mL + 36.5 mL

Volume of solution = 93.1 mL

Density of solution = 1 g/mL

Mass=1g/mL\times 93.1mL=93.1g

The mass of solution is, 93.1 grams.

Now we have to calculate the heat released in the system.

Formula used :

Q=m\times c\times \Delta T

or,

Q=m\times c\times (T_2-T_1)

where,

Q = heat released = ?

m = mass = 93.1 g

C_p = specific heat capacity of water = 4.184J/g^oC

T_1 = initial temperature  = 25.0^oC

T_2 = final temperature  = 29.83^oC

Now put all the given value in the above formula, we get:

Q=93.1g\times 4.184J/g^oC\times (29.83-25.00)^ioC

Q=1881.43J=1.88kJ        (1 kJ = 1000 J)

Now we have to calculate the moles of Ba(OH)_2 and HCl.

\text{Moles of }Ba(OH)_2=\text{Concentration of }Ba(OH)_2\times \text{Volume of solution}

\text{Moles of }Ba(OH)_2=0.266M\times 0.0365L=9.71\times 10^{-3}mol

and,

\text{Moles of }HCl=\text{Concentration of }HCl\times \text{Volume of solution}

\text{Moles of }HCl=0.648M\times 0.0566L=3.66\times 10^{-2}mol

Now we have to calculate the limiting and excess reagent.

The balanced chemical reaction is,

Ba(OH)_2+2HCl\rightarrow BaCl_2+2H_2O

From the balanced reaction we conclude that

As, 1 mole of Ba(OH)_2 react with 2 mole of HCl

So, 9.71\times 10^{-3}  moles of Ba(OH)_2 react with 9.71\times 10^{-3}\times 2=0.0194 moles of HCl

From this we conclude that, HCl is an excess reagent because the given moles are greater than the required moles and Ba(OH)_2 is a limiting reagent and it limits the formation of product.

Now we have to calculate the moles of H_2O

From the reaction, we conclude that

As, 1 mole of Ba(OH)_2 react to give 2 mole of H_2O

So, 9.71\times 10^{-3}  moles of Ba(OH)_2 react with 9.71\times 10^{-3}\times 2=0.0194 moles of H_2O

Now we have to calculate the change in enthalpy of the reaction.

\Delta H_{rxn}=-\frac{q}{n}

where,

\Delta H_{rxn} = enthalpy of reaction = ?

q = heat of reaction = 1.88 kJ

n = moles of reaction = 0.0194 mole

Now put all the given values in above expression, we get:

\Delta H_{rxn}=-\frac{1.88kJ}{0.0194mole}=-96.9kJ/mole

The negative sign indicates that the heat is released.

Therefore, the enthalpy of reaction (\Delta H_{rxn}) is, -96.9 kJ/mole

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\Delta_{\text{r}}H^{\circ} = \sum \Delta_{\text{f}} H^{\circ} (\text{products}) - \sum\Delta_{\text{f}}H^{\circ} (\text{reactants})

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ΔfH°/kJ·mol⁻¹:         0         -824.3         -1675.7         0

\begin{array}{rcl}\Delta_{\text{r}}H^{\circ} & = & [1(-1675.7) + 2(0)] - [2(0) - 1(-824.3)]\\& = & -1675.7 + 824.3\\& = & \textbf{-851.4 kJ/mol}\\\end{array}\\\text{The enthalpy change is } \large \boxed{\textbf{-851.4 kJ/mol}}

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