1. Physical
2. Chemical
3. Physical
4. Physical
5. Chemical
6. I really don't feel like doing 6, sorry.
7. False: energy to mass
11. False: change to exothermic
12. False: change to endothermic
Explanation:
21. The given molecule for cracking is tetradecane.
On cracking it forms one mole of decane (C10H22) and two moles of ethene gas.
The chemical equation is shown below:
22. The essential condition for the formation of an ester is the reaction of alcohol and acid in presence of concentrated sulfuric acid.
Thus among the given options, the first option is the correct one.
23. Isomers of butanol are shown below:
It is 2-butanol.
The position of -OH group changes to the second carbon.
I think it’s 7.41 because you count up all the atoms and find out how many are x (the large grey ones) and you do 2/27 x 100 which gives you 7.41 :) (sorry if i counted wrong it’s kinda hard)
<span>5.5×10−2M in calcium chloride and 8.0×10−2M in magnesium nitrate.
What mass of sodium phosphate must be added to 1.5L of this solution to completely eliminate the hard water ion
1) Content of Ca (2+) ions
Calcium chloride = CaCl2
Ionization equation: CaCl2 ---> Ca (2+) + 2 Cl (-)
=> Molar ratios: 1 mol of CaCl2 : 1 mol Ca(2+) : 2 mol Cl(-)
Calculate the number of moles of CaCl2 in 1.5 liters of 5.5 * 10^-2 M solution
M = n / V => n = M*V = 5.5 * 10^ -2 M * 1.5 l = 0.0825 mol CaCl2
=> 0.0825 mol Ca(2+)
2) Number of phosphate ions needed to react with 0.0825 mol Ca(2+)
formula of phospahte ion: PO4 (3-)
molar ratio: 2PO4(3-) + 3Ca(2+) = Ca3 (PO4)2
Proportion: 2 mol PO4(3-) / 3 mol Ca(2+) = x / 0.0825 mol Ca(2+)
=> x = 0.0825 coml Ca(2+) * 2 mol PO4(3-) / 3 mol Ca(2+) = 0.055 mol PO4(3-)
3) Content of Mg(2+) ions
Ionization equation: Mg (NO3)2 ----> Mg(2+) + 2 NO3 (-)
Molar ratios: 1 mol Mg(NO3)2 : 1 mol Mg(2+) + 2 mol NO3(-)
number of moles of Mg(NO3)2 in 1.5 liter of 8.0 * 10^-2 M solution
n = M * V = 8.0 * 10^ -2 M * 1.5 liter = 0.12 moles Mg(NO3)2
ions of Mg(2+) = 0.12 mol Mg(NO3)2 * 1 mol Mg(2+) / mol Mg(NO3)2 = 0.12 mol Mg(2+)
4) Number of phosphate ions needed to react with 0.12 mol Mg(2+)
2PO4(3-) + 3Mg(2+) = Mg3(PO4)2
=> 2 mol PO4(3-) / 3 mol Mg(2+) = x / 0.12 mol Mg(2+)
=> x = 0.12 * 2/3 mol PO4(3-) = 0.16 mol PO4(3-)
5) Total number of moles of PO4(3-)
0.055 mol + 0.16 mol = 0.215 mol
6) Sodium phosphate
Sodium phosphate = Na3(PO4)
Na3PO4 ---> 3Na(+) + PO4(3-)
=> 1 mol Na3PO4 : 1 mol PO4(3-)
=> 0.215 mol PO4(3-) : 0.215 mol Na3PO4
mass in grams = number of moles * molar mass
molar mass of Na3 PO4 = 3*23 g/mol + 31 g/mol + 4*16 g/mol = 164 g/mol
=> mass in grams = 0.215 mol * 164 g/mol = 35.26 g
Answer: 35.26 g of sodium phosphate
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