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Elden [556K]
2 years ago
15

1) How many liters of carbon dioxide gas will be produced at 32°C and 747 mmHg if 1.595 kg of calcium carbonate decomposes? (cal

cium oxide is the other product)
2) If 175.0mL of a 2.12M potassium chloride solution is mixed with 95.0mL of a 5.97M lead (II) nitrate solution, how many grams of precipitate will be produced in this reaction?
Chemistry
1 answer:
harina [27]2 years ago
8 0

Answer:

1. V_{CO_2}=405.85L

2. m_{PbCl_2}=51.6gPbCl_2

Explanation:

Hello,

1) In this case, the reaction is:

CaCO_3\rightarrow CaO+CO_2

Thus, since 1.595 kg of calcium carbonate, whose molar mass is 100 g/mol, is decomposed, the following moles of carbon dioxide are produced:

n_{CO_2}=1.595kgCaCO_3*\frac{1000gCaCO_3}{1kgCaCO_3}*\frac{1molCaCO_3}{100gCaCO_3} *\frac{1molCO_2}{1molCaCO_3} \\\\n_{CO_2}=15.95molCO_2

Then, by using the ideal gas equation we can compute the volume of carbon dioxide:

V_{CO_2}=\frac{n_{CO_2}RT}{P}=\frac{15.95molCO_2*0.082\frac{atm*L}{mol*K}*(32+273)K}{747mmHg*\frac{1atm}{760mmHg} }  \\\\V_{CO_2}=405.85L

2) In this case, the reaction is:

2KCl(aq)+Pb(NO_3)_2(aq)\rightarrow PbCl_2(s)+2KNO_3(aq)

Thus, lead (II) chloride is the precipitate. In such a way, we first identify the limiting reactant by firstly computing the moles of potassium chloride and lead (II) nitrate with the volumes and the molarities:

n_{KCl}=2.12mol/L*0.175L=0.371molKCl\\n_{Pb(NO_3)_2}=5.97mol/L*0.095L=0.567molPb(NO_3)_2

Next, we compute the moles of potassium chloride consumed by 0.567 moles of lead (II) nitrate by using their 2:1 molar ratio:

n_{KCl}^{consumed\ by\ Pb(NO_3)_2}=0.567molPb(NO_3)_2*\frac{2molKCl}{1molPb(NO_3)_2}=1.134molKCl

Therefore, as just 0.371 moles of potassium chloride are available we say it is the limiting reactant, for that reason, the grams of lead (II) chloride, whose molar mass is 278.1 g/mol, precipitate finally result:

m_{PbCl_2}=0.371molKCl*\frac{1molPbCl_2}{2molKCl}*\frac{278.1gPbCl_2}{1molPbCl_2} \\\\m_{PbCl_2}=51.6gPbCl_2

Best regards.

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